Adsorption, activated carbon manganese oxides

Adsorption by carbon, which is one of the oldest adsorption methods used, has been reviewed and evaluated for the preconcentration of trace metals (794). Many authors have discussed the preparation of activated charcoal and carbon from a wide variety of usually local sources. The applications to water treatment are far too numerous to mention other than a few. Jo (795) carbonized a resin and a gum and hydrated the residue above 600 C to produce an adsorbant selective for cadmium(II). Kuzin et al, 196) used deashed active carbon and oxidized carbon for the quantitative sorption of copper, lead, zinc, and nickel from nearly neutral solutions containing 1-2 M alkali-metal halide. Pearson and Siviour (797) converted the metal-ion species to amine complexes before adsorbing these onto carbonaceous materials such as brown charcoal char or cellulose. Mercury vapor can be removed from a solution by reduction followed by passage of a nitrogen stream and adsorption by activated charcoal (798). Activated carbon, which had been oxidized with nitric acid, has been used to extract several metals including divalent nickel, cadmium, cobalt, zinc, manganese, and mercury from fresh water, brine, and seawater (799, 200). 

Alternatives most frequently considered for taste and odor removal include breakpoint chlorination, aeration, ozonation, and oxidation with chlorine dioxide or potassium permanganate. None of these technologies have been found to approach the activated carbon adsorption process iri terms of effective treatment for this particular water quality problem. Another alternative is sorption onto other solids such as bleaching clays, synthetic resins or manganese dioxide. A brief summary of the advantages, disadvantages and cost factors associated with adsorption and alternative treatments for removal of tastes and odors... 

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