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Adaptation to the study

Film-forming chemical reactions and the chemical composition of the film formed on lithium in nonaqueous aprotic liquid electrolytes are reviewed by Dominey [7], SEI formation on carbon and graphite anodes in liquid electrolytes has been reviewed by Dahn et al. [8], In addition to the evolution of new systems, new techniques have recently been adapted to the study of the electrode surface and the chemical and physical properties of the SEI. The most important of these are X-ray photoelectron spectroscopy (XPS), SEM, X-ray diffraction (XRD), Raman spectroscopy, scanning tunneling microscopy (STM), energy-dispersive X-ray spectroscopy (EDS), FTIR, NMR, EPR, calorimetry, DSC, TGA, use of quartz-crystal microbalance (QCMB) and atomic force microscopy (AFM). [Pg.420]

The specific methods discussed in this chapter are representative of those which have found use in the study of mass transport in systems of pharmaceutical interest. Many of these methods represent updated versions of methods taken from the biological, chemical, and engineering sciences and adapted to the study... [Pg.103]

The anisotropic multidimensional chord distribution (CDF) is an advancement of the IDF which is adapted to the study of highly anisotropic materials. CLD, IDF, and CDF are all based on the edge-enhancement principle devised by Mering and... [Pg.167]

In our laboratory we perform experiments adapted to the study of diffusion chemical reaction phenomena under maintained nonequilibrium conditions. [Pg.52]

As carbohydrates are very sensitive to modifications of the environment, especially when they are in solution, it is of interest to focus attention on molecular interactions in aqueous solution. Vibrational spectroscopy has been shown31 33 to be one of the techniques most adapted to the study of hydrogen bonding, which is the indicator of molecular interaction in aqueous solutions of sugars. [Pg.9]

The same method has been adapted to the study of the triplet transition by looking for an excited-state orbital which is antisymmetric in the space coordinates, and is therefore of the form ... [Pg.10]

NMR spectroscopy has been adapted to the study of relaxation, because the excited atoms return to their respective ground states at definite rates, depending on the nuclear environment (Gidley, 1992). Harris et al. (1995) presented a synopsis of the potential use and limitations of NMR applied to... [Pg.141]

Double refraction of flow measurements. These also give a measurement of rotary diffusion constant and are especially adapted to the study of highly asymmetrical molecules. [Pg.121]

The methodology used in chemical engineering to describe the performance of chemical reactors can be adapted to the study of electrochemical cells. Electrosynthesis of a variety of industrially relevant products has been studied for instance, the synthesis of ammonia from natural gas at atmospheric pressure (Marnellos et al., 2001 Wang et al., 2007). [Pg.265]

Model reaction. A Geomecanique microtest unit adapted to the study of reactions giving rise to a rapid catalyst deactivation wa used (22). The reaction was conducted at a total pressure of 10 kPa with a cyclohexene partial pressure of 0.2- 10 kPa, contact times in the range 0.5 to 1.5 s, at 643 K. Sampling was performed at various times on stream (2, 5, 8, 11 min). [Pg.99]

It is also possible to define a set of N molecules in a different way, by listing the molecules contained in , and this other representation is more adapted to the study of sets of homogeneous polymers. [Pg.345]

For long polymer chains in dilute solutions, the osmotic pressure is always very weak, and the reasons for this are as follows. In order to keep the solution dilute when M increases, one must diminish the mass concentration p when p decreases at fixed molecular mass, the pressure decreases finally, when M increases at fixed p, the pressure decreases again. In conclusion, measurements of osmotic pressure are not adapted to the study of the asymptotic state of polymers in dilute solutions. [Pg.770]

It is clear that tremendous developments have been made in recent years with certain techniques. A large number of spectroscopic techniques are now available that can be adapted, with little or no adaptation, to the study of various aspects of adhesive bonding. [Pg.423]

This technique, called impedance spectroscopy, has found wide application in electrochemistry of liquids and was later adapted to the study of solids by J.E. Bauerle. [Pg.191]

The essential operating conditions which characterize the setting up of a GPTR are the time of the reaction tj., the temperature Tj. and the pressure Pj.. Table 1 gives the areas of study which can be explored by the six main laboratory reactors this table therefore allows the reactor best adapted to the study being envisaged, to be chosen. [Pg.245]

The direct sequencing of rRNA has been developed by Qu et al. (1983) for the 28S rRNA and adapted to the study of 16S-like rRNAs hy Lane et al. (1985). Radioactive labelling of the neosynthetized cDNA is achieved through a kination of the primer or through incorporation of the radionucleotide during the elongation reaction. [Pg.374]

One of the most attractive aspects of FTIR spectroscopy is its ability to deal with a great number of sampling techniques, making it a versatile method which can be adapted to the study of a wide range of materials. [Pg.11]


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