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Aconitum heterophyllum

The Structure of Atidine.—An X-ray crystallographic analysis of atidine [C22H33NO3 m.pt 182.3—183.5 °C] has been reported.21 This compound has been isolated from plants of Aconitum heterophyllum Wall. Its structure was solved by direct phasing methods and refined to a final R of 0.045. Since atidine... [Pg.207]

Delphinium cardinale, D. denudatum Aconitum heterophyllum Chemically correlated with hetisine Refs. 80, 120, 126, 127... [Pg.200]

Alkaloids of Aconitum heterophyllum Wall.—The nature of acid-catalysed rearrangement of hetisine (61), an alkaloid isolated from A. heterophyllum and Delphinium cardinale, eluded researchers for a number of years. A compound (m.pt 278—279.5 °C) with the same molecular formula as hetisine, i.e. C20H27NO3, was isolated from A. heterophyllum. This same compound was formed by treatment of hetisine with 5% sulphuric acid.24 Wiesner and co-workers2S observed an acid-catalysed rearrangement in the formation of a methiodide of hetisine. They proposed structure (62) for this rearrangement product. [Pg.258]

Aconitum heterophyllum Wall, ex Royle, Ranunculaceae Atish Root Fever, cold and cough, diarrhea, piles... [Pg.260]

Aconitum heterophyllum Chemical, spectral, and X-ray analysis Refs. 142, 183... [Pg.91]

Heteratisine.—A detailed report on the chemical elucidation of the structure and stereochemistry of heteratisine (19) has appeared. This lactone diterpenoid alkaloid has been isolated along with its monobenzoyl ester from the roots of Aconitum heterophyllum Wall. Heteratisine has not been detected in any other plant. An earlier 2f-ray crystallographic analysis of the hydrobromide monohydrate of heteratisine indicated the identical structure. Heteratisine thus bears a closer structural relationship to the highly toxic and polyoxygenated alkaloids of the lycoctonine-aconitine type than to its companion bases atisine, atidine, and hetisine. [Pg.233]

The Minor Alkaloids of Aconitum heterophyllum Hetisine, Heteratisine,... [Pg.275]

Atisane is the basic skeleton of various diterpene alkaloids (aconitum-alkaloids) found in the plant families of Ranunculaceae and Garryaceae. (-)-Atisine, as a typical representative, was isolated from the Atis plant Aconitum heterophyllum (Ranunculaceae), which also contains (-)-15,20-dihydroxy-16-atisen-19-oic acid as the lactone (19,20-olide). Erythroxylon monogynum and related speeies are reported to contain (-)-16-atisene. Euphorbiaceae such as Euphorbia acaulis and E. fidjiana produce (-)-16a,17-dihydroxyatisan-3-one. (+)-13-Atisene-16p,17-diol is known as serradiol due to its natural occurrence in Sideritis serrata (Labiatae). [Pg.66]

Atisine Aconitum heterophyllum, Aconitum anthora Ranunculaceae... [Pg.416]

Aconitum heterophyllum Berberis aristata Cissampelos pareira Curcuma longa Cyperus rotundas Aleatory cardomonium Emblica officinalis Picrorrhiza kurroa Plumbago zeylenica Saussurea lappa Semicarpus anacardum Terminalia bellerica Terminalia chebula... [Pg.316]

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See also in sourсe #XX -- [ Pg.364 ]

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See also in sourсe #XX -- [ Pg.91 , Pg.92 ]

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See also in sourсe #XX -- [ Pg.279 , Pg.280 , Pg.284 ]



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