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Acetylenes bromination

Acetylene Bromine, chlorine, brass, copper and copper salts, fluorine, mercury and mercury salts, nitric acid, silver and silver salts, alkali hydrides, potassium metal... [Pg.1207]

A powerful oxidizer. Explosive reaction with acetaldehyde, acetic acid + heat, acetic anhydride + heat, benzaldehyde, benzene, benzylthylaniUne, butyraldehyde, 1,3-dimethylhexahydropyrimidone, diethyl ether, ethylacetate, isopropylacetate, methyl dioxane, pelargonic acid, pentyl acetate, phosphoms + heat, propionaldehyde, and other organic materials or solvents. Forms a friction- and heat-sensitive explosive mixture with potassium hexacyanoferrate. Ignites on contact with alcohols, acetic anhydride + tetrahydronaphthalene, acetone, butanol, chromium(II) sulfide, cyclohexanol, dimethyl formamide, ethanol, ethylene glycol, methanol, 2-propanol, pyridine. Violent reaction with acetic anhydride + 3-methylphenol (above 75°C), acetylene, bromine pentafluoride, glycerol, hexamethylphosphoramide, peroxyformic acid, selenium, sodium amide. Incandescent reaction with alkali metals (e.g., sodium, potassium), ammonia, arsenic, butyric acid (above 100°C), chlorine trifluoride, hydrogen sulfide + heat, sodium + heat, and sulfur. Incompatible with N,N-dimethylformamide. [Pg.365]

AtUUtiou of bromine fluoride to acetylenes. Bromine fluoride reacts with terminal alkynes by Markownikoff addition ... [Pg.48]

Bromine. Slip the glass cover of a jar momentarily aside, add 2-3 ml. of bromine water, replace the cover and shake the contents of the jar vigorously. Note that the bromine is absorbed only very slowly, in marked contrast to the rapid absorption by ethylene. This slow reaction with bromine water is also in marked contrast to the action of chlorine water, which unites with acetylene with explosive violence. (Therefore do not attempt this test with chlorine or chlorine water.)... [Pg.87]

Phenylpropiolic acid. This is an example of an aromatic acetylenic acid, and is made by adding bromine to the ethylenio linkage in ethyl cinnamate, and treating the resulting dibromide with alcohobc potassium hydroxide which eliminates two molecules of hydrogen bromide ... [Pg.755]

Iodine Acetaldehyde, acetylene, aluminum, ammonia (aqueous or anhydrous), antimony, bromine pentafluoride, carbides, cesium oxide, chlorine, ethanol, fluorine, formamide, lithium, magnesium, phosphorus, pyridine, silver azide, sulfur trioxide... [Pg.1209]

Hypohahtes replace the acetylenic hydrogen with chlorine, bromine, or iodine (203). [Pg.113]

Acetylene is condensed with carbonyl compounds to give a wide variety of products, some of which are the substrates for the preparation of families of derivatives. The most commercially significant reaction is the condensation of acetylene with formaldehyde. The reaction does not proceed well with base catalysis which works well with other carbonyl compounds and it was discovered by Reppe (33) that acetylene under pressure (304 kPa (3 atm), or above) reacts smoothly with formaldehyde at 100°C in the presence of a copper acetyUde complex catalyst. The reaction can be controlled to give either propargyl alcohol or butynediol (see Acetylene-DERIVED chemicals). 2-Butyne-l,4-diol, its hydroxyethyl ethers, and propargyl alcohol are used as corrosion inhibitors. 2,3-Dibromo-2-butene-l,4-diol is used as a flame retardant in polyurethane and other polymer systems (see Bromine compounds Elame retardants). [Pg.393]

CH3) 2CBrCHBrCH3 + H2O (CH3) 2CHCOCH3 + 2 HBr In the presence of base, bromine reacts with acetylenes to displace a hydrogen (28). [Pg.283]

Pyrolysis. Pyrolysis of 1,2-dichloroethane in the temperature range of 340—515°C gives vinyl chloride, hydrogen chloride, and traces of acetylene (1,18) and 2-chlorobutadiene. Reaction rate is accelerated by chlorine (19), bromine, bromotrichloromethane, carbon tetrachloride (20), and other free-radical generators. Catalytic dehydrochlorination of 1,2-dichloroethane on activated alumina (3), metal carbonate, and sulfate salts (5) has been reported, and lasers have been used to initiate the cracking reaction, although not at a low enough temperature to show economic benefits. [Pg.7]

Acetylene works Acrylates works Aldehyde works Aluminum works Amines works Ammonia works Anhydride works Arsenic works Asbestos works Benzene works Beryllium works Bisulfate works Bromine works Cadmium works Carbon disulfide works Carbonyl works Caustic soda works Cement works Ceramic works Chemical fertilizer works Chlorine works Chromium works Copper works Di-isocyanate works Electricity works Fiber works Fluorine works Gas liquor works Gas and coke works Hydrochloric acid works Hydrofluoric acid works Hydrogen cyanide works Incineration works Iron works and steel works... [Pg.755]

Replacement, of acetylenic hydrogen atom by bromine, 46, 86 of acyl chlorine atom by fluoride atom using hydrogen fluoride, 46, 3... [Pg.137]

Some diamines carrying very bulky substituents like cardo groups can give colorless polyimides. For example, the bis-9,9-(4-aminophenyl)fluorene (FDA) or brominated and acetylenic FDA derivatives react with 6FDA giving copolymer films62 with low birefringence (low difference between in-plane and out-of-plane refraction index) (Fig. 5.8). A new cardo diamine l,l-bis[4-(4-aminophenoxy)phenyl]cyclododecane (Fig. 5.8) reacts with different aromatic dianhydrides with formation of colorless polyimides.63... [Pg.277]

Acetylene compounds Dicobaltoctacarbonyl Formation of colored complexes. After the reagent excess has been washed out, reaction with bromine vapor yields cobalt bromide, which reacts with a-nitroso-P-naphthol to yield red chromatogram zones on an almost colorless background. [11]... [Pg.31]

Scheme 24 Unusually high reactivity of the triple bond of acetylene dicarboxylate in the bromination... Scheme 24 Unusually high reactivity of the triple bond of acetylene dicarboxylate in the bromination...
Recent studies by Pincock and Yates (32, 33) have demonstrated the intermediacy of vinyl cations in the electrophilic bromination of arylmethyl-acetylenes in acetic acid. The rates of addition of Brj to a number of substituted phenylmethylacetylenes in acetic acid follow the general equation... [Pg.214]

Acetylene Chlorine, bromine, copper, silver, flourine or mercury... [Pg.158]

Bromine Ammonia, acetylene, butadiene, butane or other petroleum gases, sodium carbide, turpentine, benzene, or finely-divided metals... [Pg.158]

Violent reactions have occurred between ozone and many chemicals, a small selection being acetylene, alkenes, dialkyl zincs, benzene/rubber solution, bromine, carbon monoxide and ethylene, diethyl ether, hydrogen bromide, and nitrogen oxide. [Pg.304]

A much faster reaction for bromides than chlorides usually suggests attack on halogen, since bromine is more readily attacked by nucleophilic phosphorus. However, for phenyl acetylenes (82 = Ph) these rates... [Pg.83]

Action of bromine on acetylene, action of nitric acid on aromatic hydrocarbons. The accidents involving both reactions are very specific.They are the result of application of an unsuitable temperature. If it is too low, the reaction is too slow and causes an accumulation of reagent that is not converted and whose concentration increases, causing an acceleration of the reaction, i.e. a rise in temperature. The temperature then becomes too high and causes a more or less violent speeding-up of the reaction. [Pg.149]

Two examples have been given for the temperature/concentration action in the earlier reference to thermal effects (actions of bromine on acetylene and nitric acid on aromatic hydrocarbons). [Pg.150]


See other pages where Acetylenes bromination is mentioned: [Pg.211]    [Pg.558]    [Pg.623]    [Pg.632]    [Pg.635]    [Pg.706]    [Pg.211]    [Pg.558]    [Pg.623]    [Pg.632]    [Pg.635]    [Pg.706]    [Pg.1071]    [Pg.115]    [Pg.40]    [Pg.362]    [Pg.397]    [Pg.374]    [Pg.28]    [Pg.458]    [Pg.67]    [Pg.341]    [Pg.430]    [Pg.943]    [Pg.35]    [Pg.151]    [Pg.693]    [Pg.240]    [Pg.1071]   
See also in sourсe #XX -- [ Pg.310 ]




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Bromination of acetylenes

Bromine acetylene incompatibility

Bromine, acetylene action

Replacement, of acetylenic hydrogen atom by bromine

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