Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

A Theoretical Note

Dll. Dixon, M., and Webb, E. C., Enzyme fractionation by salting-out A theoretical note. Advan. Protein Chem. 16, 197-219 (1961). [Pg.286]

Polyamic acids are useful resists especially when containing 2,2 -dinitrodi-phenylmethane segments, while a Ti sapphire laser has been found to be effective for 3D curing and microfabrication. On a theoretical note, a direct correlation has been found between the calculated Boltzmann-averaged dipole moment and the measured maximum rate of photoinitiated radical polymerization of acrylic monomers. ... [Pg.239]

The limiting compression (or maximum v value) is, theoretically, the one that places the film in equilibrium with the bulk material. Compression beyond this point should force film material into patches of bulk solid or liquid, but in practice one may sometimes compress past this point. Thus in the case of stearic acid, with slow compression collapse occurred at about 15 dyn/cm [81] that is, film material began to go over to a three-dimensional state. With faster rates of compression, the v-a isotherm could be followed up to 50 dyn/cm, or well into a metastable region. The mechanism of collapse may involve folding of the film into a bilayer (note Fig. IV-18). [Pg.116]

The term theoretical chemistry may be defined as the mathematical description of chemistry. The term computational chemistry is generally used when a mathematical method is sufficiently well developed that it can be automated for implementation on a computer. Note that the words exact and perfect do not appear in these definitions. Very few aspects of chemistry can be computed exactly, but almost every aspect of chemistry has been described in a qualitative or approximately quantitative computational scheme. The biggest mistake a computational chemist can make is to assume that any computed number is exact. However, just as not all spectra are perfectly resolved, often a qualitative or approximate computation can give useful insight into chemistry if the researcher understands what it does and does not predict. [Pg.1]

Figure 8.3 Volume fraction polymer in equilibrium phases for chains of different length, (a) Theoretical curves drawn for the indicated value of n, with the interaction parameter as the ordinate. Note that x increases downward. (Redrawn from Ref. 6.) (b) Experimental curves for the molecular weights indicated, with temperature as the ordinate. [Reprinted with permission from A. R. Shultz and P. J. Flory, J. Am. Chem. Soc. 74 4760 (1952), copyright 1952 by the American Chemical Society.]... Figure 8.3 Volume fraction polymer in equilibrium phases for chains of different length, (a) Theoretical curves drawn for the indicated value of n, with the interaction parameter as the ordinate. Note that x increases downward. (Redrawn from Ref. 6.) (b) Experimental curves for the molecular weights indicated, with temperature as the ordinate. [Reprinted with permission from A. R. Shultz and P. J. Flory, J. Am. Chem. Soc. 74 4760 (1952), copyright 1952 by the American Chemical Society.]...
Figure 9.4b shows a theoretical f/fQ contour for a value of this ratio equal to 1.45. As noted in the discussion of this figure in Sec. 9.3, the intersection of the f/fQ and [77] contours permits the state of solvation and ellipticity of such a protein molecule to be characterized uniquely. [Pg.627]

Normal mode analysis provides a good example of information which is obtainable only through a theoretical calculation, since spectroscopic data does not directly indicate the specific type of nuclear motion producing each peak. Note that it is also possible to animate vibrational modes in some graphics packages. [Pg.66]

M. Amon and C. D. Denson [33-34] attempted a theoretical and experimental examination of molding a thin plate from foamed thermoplastic. In the first part of the series [33] the authors examined bubble growth, and in the second [34] — used the obtained data to describe how the thin plate could be molded with reference to the complex situation characterized in our third note. Here, we are primarily interested in the model of bubble growth per se, and, of course, the appropriate simplification proposals [33]. Besides the conditions usual for such situations ideal gets, adherence to Henry s law, negligible mass of gas as compared to mass of liquid, absence of inertia, small Reynolds numbers, incompressibility of liquid, the authors postulated [33] several things that require discussion ... [Pg.108]

A 2-1. three-necked flask fitted with a stirrer (Notes 1 and 2), condenser, and dropping funnel (Note 3) is mounted in the hood, and in it are placed 20 g. (0.061 mole) of potassium anthra-quinone-a-sulfonate (p. 72), 500 cc. of water, and 85 cc. (1 mole) of concentrated hydrochloric acid. The solution is heated to boiling and stirred, while a solution of 20 g. (0.19 mole) of sodium chlorate (Note 4) in 100 cc. of water is added dropwise over a period of three hours (Note 5). The mixture is refluxed very slowly for an additional hour before the precipitated a-chloro-anthraquinone is collected by suction filtration and washed free from acid with hot water (about 350 cc.). After drying in vacuo at ioo°, the bright yellow product melts at 158-160° (corr.) and weighs 14.6-14.7 g. (97-98 per cent of the theoretical amount) (Notes 6 and 7). [Pg.15]

Extrapolate the results to A = 0. Note. Such extrapolation should not be done unless the integration scheme has a theoretical order of convergence that agrees with the apparent order. Assume that it does.)... [Pg.75]

The theoretical surface density of oxygen ions was evaluated by Madier el al. for different crystallographic planes of Ce02 and Ce Zr Oj oxides [14], For ceria, the theoretical O density would be of 13.7, 9.7 and 15.8at.Onm 2 for (100), (110) and (111) surfaces respectively, which gives a mean surface density of 13.1 at.O nm 2 if one assumes an equidistribution of the three crystallographic planes. This figure leads to a theoretical OSC of 5.4 p,mol O m-2. The hypothesis of equidistribution may be not valid in all cases, which can explain some difference in the reported results. Note that the (111) surface is thermodynamically the most stable [34,35],... [Pg.238]

Note that operation of a two-level laser system requires inversion of the population of the upper laser level with respect to the ground state—a theoretical impossibility under steady-state conditions if optical excitation is employed. [Pg.458]


See other pages where A Theoretical Note is mentioned: [Pg.391]    [Pg.407]    [Pg.197]    [Pg.344]    [Pg.213]    [Pg.93]    [Pg.497]    [Pg.391]    [Pg.407]    [Pg.197]    [Pg.344]    [Pg.213]    [Pg.93]    [Pg.497]    [Pg.604]    [Pg.17]    [Pg.58]    [Pg.417]    [Pg.99]    [Pg.59]    [Pg.159]    [Pg.299]    [Pg.44]    [Pg.88]    [Pg.68]    [Pg.69]    [Pg.76]    [Pg.216]    [Pg.110]    [Pg.44]    [Pg.670]    [Pg.176]    [Pg.112]    [Pg.68]    [Pg.34]    [Pg.23]    [Pg.220]    [Pg.234]    [Pg.42]    [Pg.98]    [Pg.270]    [Pg.120]    [Pg.106]    [Pg.163]   


SEARCH



Theoretical Notes

© 2024 chempedia.info