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With a Substituent at C-3 Containing More than One Carbon

Hydrangea macrophylla var. thunbergii Absolute configeration Biosynthesis Synthesis [Pg.23]

All optically active derivatives are called d or l, based on the configuration of carbon 6. The configuration of carbon 6 is found by viewing the Fischer-type projection (p. 9) with carbons 5 and 1 away from the viewer and C-5 at the top. When an optically inactive cyclitol has been made asymmetric by substitution, the d or l is put at the beginning of the name, e.g., D-l-O-methyl-mwco-inositol, but 3-0-methyl-D-inositol. When an inositol derivative contains less than six asymmetric carbon atoms, it is named as a derivative of the related inositol that has the maximum number of CIS OH groups. If this leads to more than one possibility, the parent inositol is chosen that has the lowest possible number for its substituents CIS to the OH on carbon 1. [Pg.270]

See other pages where With a Substituent at C-3 Containing More than One Carbon is mentioned: [Pg.1]    [Pg.1]    [Pg.1]    [Pg.23]    [Pg.32]    [Pg.39]    [Pg.1]    [Pg.1]    [Pg.1]    [Pg.23]    [Pg.32]    [Pg.39]    [Pg.540]    [Pg.241]    [Pg.241]    [Pg.194]    [Pg.67]    [Pg.311]    [Pg.101]    [Pg.283]    [Pg.222]    [Pg.268]    [Pg.101]    [Pg.153]    [Pg.171]    [Pg.987]    [Pg.625]    [Pg.97]    [Pg.347]    [Pg.468]   


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At carbon

C-Substituents

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With a One-Carbon Substituent at

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