Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Vertex points

The vertex of a separation region points out the better operating conditions, since it is the point where the purity criteria are fulfilled with a higher feed flow rate (and so lower eluent flow rate). Hence, in the operating conditions specified by the vertex point, both solvent consumption and adsorbent productivity are optimized. Comparing the vertex points obtained for the two values of mass transfer coefficient, we conclude that the mass transfer resistance influences the better SMB operating conditions. Moreover, this influence is emphasized when a higher purity requirement is desired [28]. [Pg.242]

A new random number is used for each calculation resulting in a component level within its own compositional limits. The final component level is then calculated as one minus the summation of the previously determined values. If the final component is not within its own constraint limits, the process is reinitiated with a new calculation of the first component value. Each set of feasible formulation levels generated in this manner corresponds to one vertex point. The Box recommendation of using twice the number of vertices as components was followed for the formulation optimization. [Pg.62]

After each reflection or expansion step, the component levels of the new vertex point are tested to assure compliance within the individual lower and upper constraints. If during the search procedure a constraint limit is violated by a particular component, a correction factor is calculated to force the component value to remain in the feasible space at the boundary limit value. For a constraint being violated by component I, this correction factor is computed as ... [Pg.63]

The evolution of a new set of electrochemical waves (as opposed to the gradual shifting of the redox couple) on addition of guest species may be due to a number of factors. If the complex formed has a particularly high stability constant and has a redox potential which is markedly different from that of the free ligand, a new set of waves may be observed. However, if the decomplexation kinetics of the complex formed is particularly slow on the electrochemical time scale then, as the potential is scanned between the vertex points during a cyclic voltammetric experiment, the solution complexed species will be stable over this time period and the two sets of waves will correspond to free ligand and complex. Therefore care should be taken to determine the cause of the evolution of a new set of electrochemical waves and... [Pg.8]

A creation of a vertex point in a deton wave was obtd by mismatching the constituents of a plane wave expl lens, that is, by causing a delay, AtQon the axis of the lens in relation to its edge. The deton wave... [Pg.683]

Now fill in the axial and equatorial bonds. The axial bonds are drawn vertically, either up or down. When a vertex of the chair points upward, its axial bond also points upward. If the vertex points downward, its axial bond points downward. Cl is a downward-pointing vertex, and its axial bond also points downward. C2 points upward, and its axial bond points upward. [Pg.116]

Always draw the polygon with a vertex pointing down ... [Pg.629]

Table 3.11 lists the real forms for the U and spherical X = 0) and vector (X = 1 ) harmonics for the 1 = 0 to 3 central harmonic functions. Group orbitals of the particular irreducible symmetries for which these central functions provide bases follow simply by making linear combinations of the u and vj at each vertex point modulated by the values of Uj and to form local resultants, which interconvert from vertex to vertex of the orbit under the actions of the symmetry operations of the point group. [Pg.92]

There are four solutions in the general case of an interseetion of two conics. In our case there are not more than two possible solutions. This oeeurs because the diffraetion and reflection cones have the same vertex-point A2. Let us denote by the angle between the axes of the diffraction and reflection cones. These eones will intersect with one another... [Pg.199]

If all the areas 5, ..., Sm of the vertex point s branches have the same order of mztgiii-tude i9i = ni5 ... Sm — (nj,..., um finite), more simple renormalization factors... [Pg.668]

In order to treat the Hex-Z geometry of FBR cores more accurately, effort to develop a neutron transport code based on an improved nodal method was continued. In the previous version of the nodal code, the radial transverse leakage on node boundaries was assumed to be distributed uniformly, which generates some truncation errors. This year, a new treatment for the radial transverse leakage was introduced to the code by adopting a second order polynomial expansion of the flux at the node vertex point. A benchmark test of an FBR core showed the new nodal method can predict the keff within errors of 0.02%dk/k, on the other hand, the previous treatment has errors of 0.1%dk/k. [Pg.153]

The wire-frame representation of a three-dimensional object consists of a three-dimensional vertex point list and an edge list of vertex pairs. Although this representation is very simple, it is an ambiguous representation for determining such quantities as surface area and volume of an object. Wire-frame... [Pg.2078]

Vertex, point where links meet in a net or polyhedron. [Pg.15]

The simulation of a randomly oriented EPR spectrum involves integration over a unit sphere (Eq. (3)) that is performed numerically by partitioning a unit sphere and calculating the resonant field positions and transition probabilities at all of flie vertex points. [Pg.150]

In the SOPHE grid there are TV curves in each set, with the number of grid points varying from 2 to TV + 1 in steps of 1. In order to produce simulated spectra of high quality, the unit sphere is often required to be finely partitioned, in other words, a large number of vertex points are required to reduce computational noise... [Pg.150]

Part (a) The feed containing 37.5% acetic acid is shown as point F on the AC arm of the triangle. Since the solvent is pure isopropyl ether, point S concides with the vertex point B, pure solvent. Join this point with 0.02 on the AC coordinate, point Rj, corresponding to the solvent-free rafflnate prodnct it intersects the Ucr vs. Uq curve at Join Rn to B and extend it. Then have the tie line, which, when extended to the left, hits point F on AC extended to the right this line will intersect the RjjB line at Ajtm- This tie line will provide the minimum value of the extract phase flow rate line RimRjv intersects line FB at point where = 0.168. Represent this point as KcM- Then equation (8.1.327) provides (since Ucs = 0)... [Pg.749]

In using the inscribed polygon method, always draw the vertex pointing down. [Pg.426]

Draw the inscribed pentagons with the vertex pointing down. Then draw the molecular orbitals (MOs) and add the electrons. [Pg.427]

Cyclooctatetraene reacts with potassium to give a stable dianion. Explain why. Inscribe the dianion in a circle, with one vertex pointed down, and draw a molecular orbital energy diagram for it. [Pg.413]

Let the centers of all the atoms in one close-packed plane be labeled A. Associated with this plane are two sets of equivalent triangular depressions formed by three adjacent atoms, into which the next close-packed plane of atoms may rest. Those having the triangle vertex pointing up are arbitrarily designated as B positions, whereas the remaining depressions are those with the down vertices, which are marked C in Figure 3.16a. [Pg.82]

The MO diagram of a cyclic conjugated n system takes the shape of the ring involved, with one vertex pointing down. For example... [Pg.330]


See other pages where Vertex points is mentioned: [Pg.454]    [Pg.454]    [Pg.241]    [Pg.253]    [Pg.254]    [Pg.62]    [Pg.63]    [Pg.43]    [Pg.434]    [Pg.461]    [Pg.11]    [Pg.28]    [Pg.481]    [Pg.89]    [Pg.391]    [Pg.39]    [Pg.256]    [Pg.127]    [Pg.499]    [Pg.458]    [Pg.469]    [Pg.527]    [Pg.435]    [Pg.176]    [Pg.2927]   


SEARCH



Vertices

© 2024 chempedia.info