Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Harmonic functions

The inverse problem would be well defined if we knew the temperature or the harmonic function... [Pg.137]

Thus, the harmonic function >P(2 ,y) is a function of two variables which can be determined from the boundary conditions. This follows also from the fact that If the distribution of is described only by harmonic functions, the other stress components do not develop in cylinders [2]. [Pg.138]

This term is associated with the deformation of an angle from its normal value. For small displacements from ec nilibnuni, a harmonic function is often used ... [Pg.175]

In a Urey-Bradley force field, angle bending is achieved using 1,3 non-bonded interaction rather than an explicit angle-bending potential. The stretch-bond term in such a forci field would be modelled by a harmonic function of the distance between the 1,3 atoms ... [Pg.197]

HyperChem uses harmonic functions to calculate potentials for bonds and bond angles (equation 9). [Pg.23]

Harmonic Functions Both the real and the imaginary )arts of any analytic function/= u + iij satisfy Laplaces equation d /dx + d /dy = 0. A function which possesses continuous second partial derivatives and satisfies Laplace s equation is called a harmonic function. [Pg.452]

Superposition of Flows Potential flow solutions are also useful to illustrate the effect of cross-drafts on the efficiency of local exhaust hoods. In this way, an idealized uniform velocity field is superpositioned on the flow field of the exhaust opening. This is possible because Laplace s equation is a linear homogeneous differential equation. If a flow field is known to be the sum of two separate flow fields, one can combine the harmonic functions for each to describe the combined flow field. Therefore, if d)) and are each solutions to Laplace s equation, A2, where A and B are constants, is also a solution. For a two-dimensional or axisymmetric three-dimensional flow, the flow field can also be expressed in terms of the stream function. [Pg.840]

As mentioned in Section 2.2.3, the out-of-plane energy may also be described by an improper torsional angle. For the example shown in Figure 2.6, a torsional angle ABCD may be defined, even though there is no bond between C and D. The out-of-plane oop may then be described by an angle for example as a harmonic function... [Pg.16]

A is a normalization constant and T/.m are the usual spherical harmonic functions. The exponential dependence on the distance between the nucleus and the electron mirrors the exact orbitals for the hydrogen atom. However, STOs do not have any radial nodes. [Pg.150]

A vibration is a periodic motion or one that repeats itself after a certain interval of time. This time interval is referred to as the period of the vibration, T. A plot, or profile, of a vibration is shown in Figure 43.1, which shows the period, T, and the maximum displacement or amplitude, X - The inverse of the period, j, is called the frequency, f, of the vibration, which can be expressed in units of cycles per second (cps) or Hertz (Hz). A harmonic function is the simplest type of periodic motion and is shown in Figure 43.2, which is the harmonic function for the small oscillations of a simple pendulum. Such a relationship can be expressed by the equation ... [Pg.665]

The French physicist and mathematician Jean Fourier determined that non-harmonic data functions such as the time-domain vibration profile are the mathematical sum of simple harmonic functions. The dashed-line curves in Figure 43.4 represent discrete harmonic components of the total, or summed, non-harmonic curve represented by the solid line. [Pg.665]

Figure 43.2 Small oscillations of a simple pendulum, harmonic function... Figure 43.2 Small oscillations of a simple pendulum, harmonic function...
The distribution of orientation of the structural units can be described by a function N(0, solid angle sin 0 d0 dtp d Jt. It is most appropriate to expand this distribution function in a series of generalised spherical harmonic functions. [Pg.84]

The value of y at the center of the pattern is the arithmetic mean of the values of y at the remaining four nodes of the pattern. This formula gives a difference analog of the formula for the mean value of a harmonic function. [Pg.246]

Therefore, if the function U satisfies the Laplace s equation, then it possesses a remarkable interesting feature, namely, its average value calculated around some point p is exactly equal to the value of the function at this point. A certain class of functions has this feature only, and such functions are called harmonic. Correspondingly, we conclude that the potential of the attraction field is a harmonic function outside the masses. In accordance with Laplace s equation the sum of the second derivatives along coordinate lines, v, y, and z, equals zero, provided that U(p) is a harmonic function. At the same time we know that in the one-dimensional case there is a class of functions for which the second derivative is equal to zero, that is. [Pg.25]

From this comparison of the behavior of the second derivatives, it is natural to consider harmonic functions as an analogy of the linear functions and expect that they have similar features. Let us outline some of them. [Pg.25]

It is clear that if values of a linear function are known at terminal points of some interval of x, then it can be calculated at every point inside. In the same manner, if a harmonic function is given at each point of the boundary surface surrounding the volume, it can be determined at any of its point. [Pg.25]

If a linear function has equal values at terminal points of the interval, then it has the same value inside it, that is, the linear function is constant. By analogy, if a harmonic function has same value at all points of the boundary surface, then it has the same value at any point within the volume. [Pg.25]

Of course, both statements can be proved from the theorem of uniqueness for the attraction field. In addition, it is appropriate to comment a linear function reaches its maximum at terminal points of the interval. The same behavior is observed in the case of harmonic functions, which cannot have their extreme inside the volume. Otherwise, the average value of the function at some point will not be equal to its value at this point, and, correspondingly, the Laplacian would differ from zero. At the same time, saddle points may exist. [Pg.25]

This means that Poisson s equation defines the potential with an uncertainty of a harmonic function 14. Regardless of a distribution of masses outside the volume the potential C4 remains harmonic function inside V and, correspondingly, there are an infinite number of potentials U which satisfy Equation (1.70), and they can be represented as ... [Pg.26]

This first case vividly illustrates the importance of the boundary condition. Indeed, Poisson s equation or the system of field equations have an infinite number of solutions corresponding to different distributions of masses located outside the volume. Certainly, we can mentally picture unlimited variants of mass distribution and expect an infinite number of different fields within the volume V. In other words, Poisson s equation, or more precisely, the given density inside the volume V, allows us to find the potential due to these masses, while the boundary condition (1.83) is equivalent to knowledge of masses situated outside this volume. It is clear that if masses are absent in the volume V, the potential C7 is a harmonic function and it is uniquely defined by Dirichlet s condition. [Pg.29]

Here the unit vector n and radius vector R have opposite directions. The volume V is surrounded by the surface S as well as a spherical surface with infinitely large radius. In deriving this equation we assume that the potential U p) is a harmonic function, and the Green s function is chosen in such a way that allows us to neglect the second integral over the surface when its radius tends to an infinity. The integrand in Equation (1.117) contains both the potential and its derivative on the spherical surface S. In order to carry out our task we have to find a Green s function in the volume V that is equal to zero at each point of the boundary surface ... [Pg.40]

As was shown in Chapter 1, these conditions uniquely define the function T. For determination of the disturbing potential we will make use of Poisson s integral, described in the Chapter 1, which allows one to find the harmonic function E outside the spherical surface of the radius R, Fig. 2.9b, if this function, E p), is known at points of this surface ... [Pg.123]

Here g is the gravitational field on the physical surface of the earth, y the normal field on the surface S. At the same time, dT/dv and dy/dv have the same values along line V at both surfaces. This is the boundary condition for the disturbing potential and therefore we have to find the harmonic function regular at infinity and satisfying Equation (2.301) on the surface S. In this case, the physical surface of the earth is represented by S formed by normal heights, plotted from the reference ellipsoid. In other words, by leveling the position of the surface S becomes known. [Pg.133]

Young modulus, harmonic function outside a geoid... [Pg.258]

The solutions of Laplace s equation are known as harmonic functions. In one dimension the equation... [Pg.108]

Again, V has no local maxima or minima and all extrema occur at the boundaries. Geometrically, just as the straight line is the shortest distance between two points, so a harmonic function in two dimensions minimizes the surface area fitted to the given boundary line. [Pg.109]

Instead of using harmonic functions the torsional potential is more often described with a small cosine expansion in ... [Pg.402]

Fig. 2.8. Left oscillatory part of the reflectivity change of Bi (0001) surface at 8K (open circles). Fit to the double damped harmonic function (solid curve) shows that the Aig and Eg components (broken and dotted curves) are a sine and a cosine functions of time, respectively. Right pump polarization dependence of the amplitudes of coherent Aig and Eg phonons of Bi (0001). Adapted from [25]... Fig. 2.8. Left oscillatory part of the reflectivity change of Bi (0001) surface at 8K (open circles). Fit to the double damped harmonic function (solid curve) shows that the Aig and Eg components (broken and dotted curves) are a sine and a cosine functions of time, respectively. Right pump polarization dependence of the amplitudes of coherent Aig and Eg phonons of Bi (0001). Adapted from [25]...

See other pages where Harmonic functions is mentioned: [Pg.137]    [Pg.138]    [Pg.138]    [Pg.41]    [Pg.82]    [Pg.86]    [Pg.283]    [Pg.27]    [Pg.28]    [Pg.123]    [Pg.123]    [Pg.31]    [Pg.195]    [Pg.110]    [Pg.76]    [Pg.13]   
See also in sourсe #XX -- [ Pg.25 , Pg.26 , Pg.27 , Pg.28 , Pg.40 , Pg.123 , Pg.133 ]

See also in sourсe #XX -- [ Pg.13 , Pg.23 , Pg.97 , Pg.99 , Pg.180 ]

See also in sourсe #XX -- [ Pg.108 ]

See also in sourсe #XX -- [ Pg.21 ]

See also in sourсe #XX -- [ Pg.45 ]

See also in sourсe #XX -- [ Pg.24 ]

See also in sourсe #XX -- [ Pg.89 ]

See also in sourсe #XX -- [ Pg.99 ]

See also in sourсe #XX -- [ Pg.887 , Pg.895 ]

See also in sourсe #XX -- [ Pg.13 , Pg.23 , Pg.97 , Pg.99 , Pg.180 ]

See also in sourсe #XX -- [ Pg.146 ]

See also in sourсe #XX -- [ Pg.146 , Pg.156 ]

See also in sourсe #XX -- [ Pg.25 ]




SEARCH



Basis function cubic harmonic

Basis spherical harmonic functions

Bond harmonic function

Complex functions harmonic

Complex spherical harmonic functions

Conjugate harmonic functions

Expansion of Ligand Set as Spherical Harmonic Functions

Functions and Surface Harmonics

Harmonic change, spectral function

Harmonic cosine function

Harmonic functions, periodic structures

Harmonic oscillator functions

Harmonic oscillator partition function

Harmonic oscillator wave functions

Harmonic potential function

Harmonic sine function

Harmonic wave functions

Harmonic-oscillator function, hydrogen bonds

Harmonic-oscillator function, hydrogen bonds bond vibrations

Harmonic-oscillator functions table

Legendre functions, spherical harmonics

Matsubara Harmonic Partition Function

Normalized, spherical harmonic functions

Potential functions harmonic interaction

Products of Spherical Harmonic Functions

Real spherical harmonic functions

Real spherical harmonic functions product

Selection Rules and Intensities for Surface-harmonic Wave Functions

Simple harmonic potential function

Solid Spherical Harmonic Function

Solid-harmonic functions, definition

Spherical harmonic functions

Spherical harmonic functions hydrogen atom orbitals

Spherical harmonic functions, momentum

Spherical harmonic orientation functions

Surface-harmonic wave functions

Vector harmonic functions

Vector harmonic functions decaying harmonics

Vector spherical wave functions harmonics

© 2024 chempedia.info