Vent loss

An effective way of preventing vent loss is to use one of the many types of variable-volume tanks. These are built under API Standard 650. They may have floating roofs of the double-deck or the singledeck type. There are hfter-roof types in which the roof either has a sldrt moving up and down in an annular hquid seal or is connected to the tank shell oy a flexible membrane. A fabric expansion chamber housed in a compartment on top of the tank roof also permits variation in volume. 

Split Simple Starting point for method development Use with isothermal and temperature programmed GC Fast very sharp peaks Choice of glass sleeve not trivial Limits detection concentration to ppm Most sample wasted through split vent Loss of low-volatility, labile analytes... 

Tests are conducted to determine capacity, heat transfer rates, steam economy, product losses, and cleaning cycles. Practically all the criteria of evaporator performance are obtained from differences between test measurements. Errors can result when measuring flow rates, temperatures and pressures, concentrations, and steam quality. Factors which can have a great effect on performance include dilution, vent losses, heat losses, and physical properties of fluids. 

Loss Characteristics. This relief device was tested to determine if the additional neck tube would significantly affect the loss rate of the container. The vent loss rate of a 10-liter as well as a 25-liter container was measured in three configurations center vent, annular vent, and normal vent (without the device). The rate of gas evolution from the containers at 1 atm is shown in Table II. 

Boiling point Ease of retrofit Vent losses Possibility ofNCls accumulation Reboiler temperature Reboiler heat load... 

Countercurrent flow is accomplished resulting in maximum possible subcooling of condensate. Noncondensable gases, which always exist in a condenser, are contacted with the lowest available temperature before removal. Vent losses are therefore at a minimum. 

To illustrate mathematical modeling for column material-balance control, let us first lose the conventional column of Figure 14.1. The feed, Wp, is split by the column into two parts top product, Wp, and bottom product, Wp. It is assumed that vent losses overhead are negligible. It is further assumed that the heat-transfer dynamics of both the condenser and the reboiler are negligible this will be true for most columns. Let us start at the column base and work up. For convenience the equations are written in Laplace transform notation. 

Figure 2 is a similar curve for liquid-helium storage vessels. Here, however, the tankage is assumed to operate bottled up, and performance is therefore shown in terms of pressure rise. Accordingly, the curve is based on 100-psi pressure rise over a storage period of 14 days. As a matter of interest, this rate of heat addition is equivalent to a vented loss rate of approximately 1.7 per day. Ullage was taken at 10 as with liquid hydrogen. 

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