Uranium salt

Crystals of uranium nitrate are triboluminescent. Uranium salts have also been used for producing yellow "vaseline" glass and glazes. Uranium and its compounds are highly toxic, both from a chemical and radiological standpoint. 

Homogeneous Aqueous Reactors. As a part of the research on neutron multiphcation at Los Alamos in the 1940s, a small low power reactor was built using a solution of uranium salt. Uranyl nitrate [36478-76-9] U02(N0 2> dissolved in ordinary water, resulted in a homogeneous reactor, having uniformly distributed fuel. This water boiler reactor was spherical. The 235u... 

Urano-hydroxyd, n. uranous hydroxide, ura-nium(IV) hydroxide, -reihe, /. uranous series, -salz, n. uranous salt, -uranat, n. uranous uranate, uranium(IV,VI) oxide, UaOa. -verbindung, /. uranous compound, Uran-oxyd, n. uranium oxide, specif, uranic oxide, uranium(VI) oxide, UOa. -ozydhydrat, n. uranium hydroxide, -oxydoxydul, n. = Uranoxyduloxyd. -oxydrot, n. uranium oxide red- -oxydul, n. uranous oxide, ura-nium(IV) oxide, UO2. -oxyduloxyd, n. uranoso-uranic oxide, uranium (I V,VT) oxide, UaOa. -oxydulsalz, n. uranous salt, uranium-(IV) salt, -pechblende, /., -pecherz, n. pitchblende, -phosphat, n, uranium phosphate. -rot, n. uranium red. -salz, n. uranium salt. 

Curie chose for her dissertation research the new topic of uranium rays, a phenomenon that had only recently been observed by Henri Becqiierel. The mystery was the source of the energy that allowed uranium salts to expose even covered photographic plates. Curie s first efforts in the field were systematic examinations of numerous salts to determine which salts might emit rays similar to those of Becquerel s uranium. After discovering that both thorium and uranium were sources of this radiation. Curie proposed the term radioactive to replace uranium rays. She also discovered that the intensity of the emissions depended not on the chemical... 

Marie and Irene Curie, and their husbands, Pierre Curie and Frederic Joliot. Marie Curie (1867-1934) was born Maria Sklodowska in Warsaw, Poland, then a part of the Russian empire. In 1891 she emigrated to Paris to study at the Sorbonne, where she met and married a French physicist, Pierre Curie (1859-1906). The Curies were associates of Henri Becquerel, the man who discovered that uranium salts are radioactive. They showed that thorium, like uranium, is radioactive and that the amount of radiation emitted is directly proportional to the amount of uranium or thorium in the sample. 

Complexes. The structure of an n a charge-transfer complex between quinoxaline and two iodine atoms has been obtained by X-ray analysis and its thermal stability compared with those of related complexes. The hydrogen bond complex between quinoxaline and phenol has been studied by infrared spectroscopy and compared with many similar complexes. Adducts of quinoxaline with uranium salts and with a variety of copper(II) alkano-ates have been prepared, characterized, and studied with respect to IR spectra or magnetic properties, respectively. 

The first, consisting of a uranium salt, trialkylaluminum, and a Lewis acid, had been developed at Goodyear ( 1 ). The other system, described by Snam Progetti (2), permits the polymerization of butadiene to give polymers with a cis content of up to... 

Uranium salt, C14H10O6U, uranium benzoate, uranyl benzoate. Yellow powder. Slightly sol in water, ale. 

As a result of its four oxidation states, its tendency to complex with anions and the polymeric ions formed as a result of hydrolysis, the aqueous chemistry of uranium is complex. In aqueous solutions uranium salts exhibit acidic properties as a result of hydrolysis which increases in the order U3+ < UO + < U4+. In the case of UO + at 25° the principal hydrolised species are U020H+,(U02)2 (OH) + and (UO fOHj. 

William Crookes was able to separate from uranium salts by chemical means a small quantity of an intensely radioactive substance, which he called Uranium X, the residual uranium having lost most of its activity and M. 

Uranyl nitrate is used to prepare several uranium salts. Also it is used to make uranium glaze and decorative porcelain, and as an intensifier in photography. It is an analytical reagent (e.g., Redox titration). 

In 1900 Sir William Crookes prepared a solution containing a uranium salt and a small amount of a ferric salt. When he added to this an excess of a solution containing ammonium hydroxide and ammonium carbonate, he found that the resulting ferric hydroxide precipitate was intensely radioactive. After studying the radioactive properties of the substance which precipitates with the iron, he said, For the sake of lucidity the new body must have a name. Until it is more tractable I will call it provisionally UrX—the unknown substance in uranium (30). It is now known as uranium Xi. H. N. McCoy and W. H. Ross, B. B. Boltwood, and R. B. Moore and H. Schlundt found independently that there are two uraniums, uranium 1 and uranium 2 (12, 48, 81, 108, 109, 110). 

Roentgen s discovery of x-rays stimulated great interest in this new form of radiation worldwide. Antoine Henri Becquerel (1852-1908) accidentally discovered the process of radioactivity while he was studying x-rays. Radioactivity involves the spontaneous disintegration of unstable atomic nuclei. Becquerel had stored uranium salts on top of photographic plates in a dark drawer. When Becquerel retrieved the plates, he noticed the plates contained images made by the uranium salts. Bec-querel s initial discovery in 1896 was further developed by Marie Curie (1867-1934) and Pierre Curie (1859-1906). Marie Curie coined the word radioactive to describe the emission from uranium. 

Ammino-derivatives op Molybdenum, Tungsten, and Uranium Salts. 

Two major instances of photochemical reactions that have reached deeply into modern civilization are the photosensitive silver and uranium salts and dyes which are the basis of photography and the manufacture of Vitamin D by the ultraviolet irradiation of ergosterol,... 

Fig. 1. Schematic flowsheet of uranium processing (acid leach and ion exchange) operation. Numbers refer to the numbers that appear in the boxes on the flowsheet. Operations (3), (6), (9), and (11) may be done by thickening or filtration. Most often, thickeners are used, followed by filters. The pH of the leach slurry <4) is elevated to reduce its corrosive effect and to improve the ion-exchange operation on the uranium liquor subsequently separated, In tile ion exchange operation (7), resin contained in closed columns is alternately loaded with uranium and then eluted. The resin adsorbs the complex anions, such as UC fSO 4-. in which the uranium is present in the leach solution. Ammonium nitrate is nsed for elution, obtained by recycling the uranium filtrate liquor after pH adjustment. Iron adsoibed with the uranium is eluted with it. Iron separation operation (8) is needed inasmuch as the iron hydroxide slurry is heavily contaminated with calcium sulfate and coprecipitated uranium salts. Therefore, the slurry is recycled to the watering stage (3). Washed solids from 1,6). the waste barren liquor from (7), and the uranium filtrate from (11) are combined. The pH is elevated to 7.5 by adding lime slurry before the mixture is pumped to the tailings disposal area. (Rio Algom Mines Limited, Toronto)...

The uranium and thorium ore concentrates received by fuel fabrication plants still contain a variety of impurities, some of which may be quite effective neutron absorbers. Such impurities must be almost completely removed if they are not seriously to impair reactor performance. The thermal neutron capture cross sections of the more important contaminants, along with some typical maximum concentrations acceptable for fuel fabrication, are given in Table 9. The removal of these unwanted elements may be effected either by precipitation and fractional crystallization methods, or by solvent extraction. The former methods have been historically important but have now been superseded by solvent extraction with TBP. The thorium or uranium salts so produced are then of sufficient purity to be accepted for fuel preparation or uranium enrichment. Solvent extraction by TBP also forms the basis of the Purex process for separating uranium and plutonium, and the Thorex process for separating uranium and thorium, in irradiated fuels. These processes and the principles of solvent extraction are described in more detail in Section 65.2.4, but the chemistry of U022+ and Th4+ extraction by TBP is considered here. 

Edmond Becquerel (1820-1891) was the nineteenth-century scientist who studied the phosphorescence phenomenon most intensely. Continuing Stokes s research, he determined the excitation and emission spectra of diverse phosphors, determined the influence of temperature and other parameters, and measured the time between excitation and emission of phosphorescence and the duration time of this same phenomenon. For this purpose he constructed in 1858 the first phosphoroscope, with which he was capable of measuring lifetimes as short as 10-4 s. It was known that lifetimes considerably varied from one compound to the other, and he demonstrated in this sense that the phosphorescence of Iceland spar stayed visible for some seconds after irradiation, while that of the potassium platinum cyanide ended after 3.10 4 s. In 1861 Becquerel established an exponential law for the decay of phosphorescence, and postulated two different types of decay kinetics, i.e., exponential and hyperbolic, attributing them to monomolecular or bimolecular decay mechanisms. Becquerel criticized the use of the term fluorescence, a term introduced by Stokes, instead of employing the term phosphorescence, already assigned for this use [17, 19, 20], His son, Henri Becquerel (1852-1908), is assigned a special position in history because of his accidental discovery of radioactivity in 1896, when studying the luminescence of some uranium salts [17]. 

Radioactivity was a sensation in the first decade of this century. The very concept of rays that could go right through you without you feeling a thing caused shivers of schadenfreud and for some the exposure of ones skeleton to outside view was uneasily akin to the exposure of ones soul. Conversely, the hair-loss associated with exposure to X-rays or radioactivity led to at least one clinic being set up, to which women flocked, using uranium salts as depilatory treatment. 

Later, Becquerel used an uranium salt, uranyl sulfate, K2(J02(S04)2- 2HzO, in his experiment. 

Becquerel had discovered an important property of uranium salt. He had found that uranium salt emitted radiation which penetrated black paper irregardless of sunlight. 

Antoine Henri Becquerel discovered radioactivity using uranium salts. 

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