Uranium coatings

His chamber consisted of two metal plates separated by a glass ring about 1 cm. high. The charged plates, wffich would collect the air ions, connected to a simple amplifier, which connected to an oscilloscope. To the bottom plate he attached a piece of uranium-coated foil. He set up the experiment in the basement of the institute and retrieved three of the neutron sources from the covered well. He placed the sources close to the foil and... 

The preceedlng discussion has been based on the assumption that the carbonyl group was the site of activation with the formation of a biradical. In order to verify this assumption, a controlled irradiation experiment was run. By the use of uranium coated pyrex glass, as a filter, all wavelengths below 350 n.m. were avoided. No gelation was observed even after a prolonged time period (4-5 hours). 

The heavy mineral sand concentrates are scmbbed to remove any surface coatings, dried, and separated into magnetic and nonmagnetic fractions (see Separation, magnetic). Each of these fractions is further spHt into conducting and nonconducting fractions in an electrostatic separator to yield individual concentrates of ilmenite, leucoxene, monazite, mtile, xenotime, and zircon. Commercially pure zircon sand typically contains 64% zirconium oxide, 34% siUcon oxide, 1.2% hafnium oxide, and 0.8% other oxides including aluminum, iron, titanium, yttrium, lanthanides, uranium, thorium, phosphoms, scandium, and calcium. 

MIBK is a highly effective separating agent for metals from solutions of their salts and is used in the mining industries to extract plutonium from uranium, niobium from tantalum, and zirconium from hafnium (112,113). MIBK is also used in the production of specialty surfactants for inks (qv), paints, and pesticide formulations, examples of which are 2,4,7,9-tetramethyl-5-decyn-4,7-diol and its ethoxylated adduct. Other appHcations include as a solvent for adhesives and wax/oil separation (114), in leather (qv) finishing, textile coating, and as a denaturant for ethanol formulations. 

Properties. Uranium metal is a dense, bright silvery, ductile, and malleable metal. Uranium is highly electropositive, resembling magnesium, and tarnishes rapidly on exposure to air. Even a poHshed surface becomes coated with a dark-colored oxide layer in a short time upon exposure to air. At elevated temperatures, uranium metal reacts with most common metals and refractories. Finely divided uranium reacts, even at room temperature, with all components of the atmosphere except the noble gases. The silvery luster of freshly cleaned uranium metal is rapidly converted first to a golden yellow, and then to a black oxide—nitride film within three to four days. Powdered uranium is usually pyrophoric, an important safety consideration in the machining of uranium parts. The corrosion characteristics of uranium have been discussed in detail (28). 

Fluidized-bed CVD was developed in the late 1950s for a specific application the coating of nuclear-fuel particles for high temperature gas-cooled reactors. PI The particles are uranium-thorium carbide coated with pyrolytic carbon and silicon carbide for the purpose of containing the products of nuclear fission. The carbon is obtained from the decomposition of propane (C3H8) or propylene... 

Hua et al. [595] have described an automated flow system for the constant-current reduction of uranium (VI) onto a mercury film-coated fibre electrode. Interference from iron (III) was eliminated by addition of sulfite. The results obtained for uranium (VI) in two reference seawater samples, NASS-1 and CASS-1, were 2.90 and 2.68 g/1, with standard deviations of 0.57 and 0.75 g/1, respectively. 

Salbu et al. (2003) used micro-XAS to examine oxidation of depleted uranium (DU) munitions. Interestingly, these studies revealed the presence of U02 and U3Os but no U6+ oxide hydrate phases. Brock et al. (2003) examined the corrosion of DU penetrators in an arid environment. Using SEM, they observed aggregates of tabular, hexagonal schoepite and meta-schoepite crystals with clay/silt particles that were coated with amorphous silica. Brock et al. (2003) suggested that as the schoepite/meta-schoepite phases were coated with amorphous silica/clays, further dissolution was inhibited. 

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