Unsymmetric Tetraorganotin Compounds with Olefinic Substituents

This chapter includes organotin derivatives of unsubstituted olefinic hydro-carbons. Compounds with several double bonds are reported. Compounds containing olefinic and acetylenic unsaturation in one hydrocarbon chain are included here when the olefinic bond is nearer to the tin atom. Otherwise, the compounds will be listed in Chapter 2.5 The compounds compiled in Table 103 are prepared by methods from the following scheme. 

IV Hydrogermylation reactions RnSnH4-n with dienes, allenes and acetylenes - initiated by  

V Reaction of organotin amides with acidic hydrocarbon  

R = organic group, R = unsaturated organic group, X = halogen. Additional tetraorganotin compounds with olefinic unsaturation may be found in Chapter 7.1. and 8.1. 

By-prod, in photolysis of MesSnC012)3COR, 6-2 % yield R = Me, 

---

Other unsymmetric tetraorganotin compounds with olefinic substituents are listed in Table 102. 

Table 103 Unsymmetric Tetraorganotin Compounds with Olefinic Substituents... 

---