Viscosity underfill adhesives

When the shear stress of a liquid is directly proportional to the strain rate, as in Fig. 2.4a, the liquid is said to exhibit ideal viscous flow or Newtonian behavior. Most unfilled and capillary underfill adhesives are Newtonian fluids. Materials whose viscosity decreases with increasing shear rate are said to display non-Newtonian behavior or shear thinning (Fig. 2.4b). Non-Newtonian fluids are also referred to as pseudoplastic or thixotropic. For these materials, the shear rate increases faster than the shear stress. Most fllled adhesives that can be screen printed or automatically dispensed for surface-mounting components are thixotropic and non-Newtonian. A second deviation from Newtonian behavior is shear thickening in which viscosity increases with increasing shear rate. This type of non-Newtonian behavior, however, rarely occurs with polymers. ... 

The size of the die is a further consideration in the time it takes for the underfill adhesive to traverse the distance and completely fill the gap. A plot of the square of the distance as a function of time produces a straight line as expected from Eq. (2.9) (Fig. 2.7). For a given die size, increased viscosity of the underfill material also increases the time to fill the gap. For high production rates, the fill time must be as short as possible. With increasing sizes of IC chips, this has presented... 

In the application of capillary-flow underfills, there are so many material, process, and equipment variables that empirical methods are widely used to establish the optimum processing conditions. The viscosity and flow properties of underfill adhesives are among the most important variables in rapidly filling different gap sizes and devices. A list of some commercially available underfill adhesives and their flow properties, as related to filler size and gap height, is given in Table 5.3. 

Viscosity is the internal friction that results from intermolecular forces of attraction and interactions between fillers and resins in adhesives, a measure of resistance to flow. Most adhesives are non-Newtonian fluids that exhibit shear-thinning behavior, or decrease in viscosity with increasing shear rate. Exceptions to this general rule are the capillary-flow underfill adhesives that tend to be Newtonian in fluid behavior. 

The method and type of equipment used also vary with the type of adhesive. As an example, the viscosity of electrically conductive adhesives is measured according to ASTM D1824, Apparent Viscosity of Plastisols and Organosols at Low-Shear Rates by Brookfield Viscosity The viscosity of typical electrically conductive die-attach adhesives is measured with a Brookfield HBT viscometer with Spindle TB and Speed 5. For higher-viscosity conductive adhesives and for underfill adhesives, a Brookfield RVT or RVF viscometer is used with Spindles 6 or 7 at speeds of 4—10.4 rpm. Another Brookfield viscometer, the Cone-and-plate viscometer with a CP-51 spindle is used for low-to-intermediate viscosity adhesives. Finally, the Brookfield HAT and HBT instruments are used for the high-viscosity (1-2 million cP at 1 rpm) adhesives typically used in SMT applications. ... 

Besides viscosity, the surface-wetting ability of underfills is critical to capillary flow. For capillary flow to occur, the underfill material must wet the surfaces so that the advancing contact angle is less than 90°. " Also, for capillary flow, the intramolecular forces of attraction among adhesive molecules must be weaker than the intermolecular attraction of the adhesive for the die, the substrate, and the solder surfaces.t This occurs when the surface tension of the underfill is lower than the surface energy of... 

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