Ultra-trace TNT Detection with Operable Devices

Ultra-trace TNT Detection with Operable Devices 

The unique simplicity of TNT detection by this method renders the fabrication of an operable device built around amplified fluorescent polymer technology a relatively simple proposition in comparison to other technological platforms. The method relies purely on changes in fluorescence intensity. AH that is theoretically required is a means of introducing vapor samples to a conjugated polymer film, a light source to excite the polymer film, and a photodetector to measure the emission intensity as a function of time. 

The selectivity inherent to TNT detection by amplified fluorescent polymers, as described in Section 4, helps to rriinirriize false-positives in land mine detection. These sensor devices respond only to nitroaromatics and similarly small, electron-deficient analytes, which are found typically only in or close to explosives and explosive devices. Field-tests to date have demonstrated that these devices are at least as reliable as trained dogs in detecting explosives that contain nitroaromatics. There is still uncertainty concerning what chemical that dogs actually detect when searching for explosives [17]. This 

This concept is in essence a chromatographic effect similar to that observed in gas chromatography (GC), with the conjugated polymer film acting as the stationary phase. It is possible that like in GC and other candidate technologies for explosive detection, these responses could be empirically standardized for expected analytes of interest and sensory devices caHbrated to deconvolute temporal quenching signals to determine which analytes are present. This would further enhance the selectivity of what is already a very selective sensor for TNT and related compounds. 

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