Transition metal compounds photochemistry

Geoffroy, George, L., Photochemistry of Transition Metal Hydride Complexes George, J. W., Halides and Oxyhalides of the Elements of Groups Vb and VIb George, Philip and McClure, Donald S., The Effect of Inner Orbital Splitting on the Thermodynamic Properties of Transition Metal Compounds, and... 

Electron Transfer Reactions Theory Long-range Electron Transfer in Biology Mixed Valence Compounds Molecular Orbital Theory Oxidation Catalysis by Transition Metal Complexes Photochemistry of Transition Metal Complexes Photochemistry of Transition Metal Complexes Theory. 

Asymmetric Synthesis by Homogeneous Catalysis Coordination Chemistry History Coordination Organometallic Chemistry Principles Dihydrogen Complexes Related Sigma Complexes Electron Transfer in Coordination Compounds Electron Transfer Reactions Theory Heterogeneous Catalysis by Metals Hydride Complexes of the Transition Metals Euminescence Luminescence Behavior Photochemistry of Organotransition Metal Compounds Photochemistry of Transition Metal Complexes Ruthenium Organometallic Chemistry. 

Solar Photochemistry with Transition Metal Compounds Anchored to Semiconductor Surfaces... 

SOLAR PHOTOCHEMISTRY WITH TRANSITION METAL COMPOUNDS... 

The CASPT2 approach has been used in a large variety of applications ranging from molecular structure determinations in ground and excited states [15] to calculations of binding energies of transition metal compounds [28, 29]. There is, however, little doubt that the most spectacular success of the new approach has been in electronic spectroscopy and photochemistry. Up until now, a lot of effort has been put into the refinement of computational methods for molecular ground states and it... 

This chapter reviews the major advances in the field of photochemistry and photocatalysis by transition metal compounds published in 2013-2014. Particular attention has been given to (i) photocatalysis in synthesis, and in the conversion of sunlight energy into chemical energy (ii) photoreactivity (iii) biomedical applications of photoactive transition metal complexes, e.g. as photo-CORMs and PDT agents. 

A. Maldotti, Photochemieal and Photoeatal34ic Properties of Transition-metal Compounds, in Photochemistry, A Specialistic Periodic Report, ed. A. Albini, RSC Publishing, London, 2013, vol. 41, p. 127. 

For Type lb sonochemical effects one may draw a parallel between the ability of sonication to create coordinatively unsatured transition metal complexes and the photochemical activation of resistant C-H bonds in the presence of selected transition metal complexes.22 The only problem in these cases is that one is dealing here with stoichiometric activation in most cases. In photochemistry, most of the corresponding reactions would be characterized by quantum yields smaller than 1. Examples of such reactions can be found in Ch. 2. Therefore, this type of sonochemical activation which creates active species (radicals, nitrenes, transition metal compounds with vacancies) unable to trigger a chain or a catalytic reaction should consume far more energy than Type la. 

Photochemistry of transition metal coordination compounds. A. W. Adamson, W. L. Waltz,... 

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