Toluene benzyl mercaptan

Beilstein Handbook Reference) AI3-22955 Benzenemethanethioi Benzyl hydrosuifide Benzyl mercaptan Benzylhydrosulfide Benzylthiol BRN 0605864 EINECS 202-862-5 FEMA No. 2147 HSDB 2106 Methanethiol, phenyl- NSC 41897 Phenylmethanethiol Phenylmethyl mercaptan Thiobenzyl alcohol Toluene, a-mercapto- Toluene-a-thiol USAF ex-1509. Oil mp = -30 bp = 194,5 d O = 1,068 X,m = 263, 269 nm (cyclohexane) insoluble in H2O, slightly soluble in CCI4, soluble in CS2 very soluble in EtOH, Et20. 

Phenylmercury propionate. See Phenylmercuric propionate Phenylmercury triethanolamine lactate. See Phenylmercuritriethanolammonium lactate Phenylmethanal. See Benzaldehyde Phenyl methane. See Toluene Phenylmethanethiol. See Benzyl mercaptan Phenylmethanol. See Benzyl alcohol Phenyl methicone CAS 63148-58-3... 

Toluenethiol. See o-Thiocresol 4-Toluenethiol. See p-Thiocresol a-Toluenethiol. See Benzyl mercaptan o-Toluenethiol. See o-Thiocresol p-Toluenethiol. See p-Thiocresol Toluene trichloride Toluene, a,a,a-trichloro. 

Kennedy and Stock reported the first use of Oxone for many common oxidation reactions such as formation of benzoic acid from toluene and of benzaldehyde, of ben-zophenone from diphenyhnethane, of frawi-cyclohexanediol Ifom cyclohexene, of acetone from 2-propanol, of hydroquinone from phenol, of e-caprolactone from cyclohexanone, of pyrocatechol from salicylaldehyde, of p-dinitrosobenzene from p-phenylenediamine, of phenylacetic acid from 2-phenethylamine, of dodecylsulfonic acid from dodecyl mercaptan, of diphenyl sulfone from diphenyl sulfide, of triphenylphosphine oxide from triphenylphosphine, of iodoxy benzene from iodobenzene, of benzyl chloride from toluene using NaCl and Oxone and bromination of 2-octene using KBr and Oxone . Thus, they... 

The synthesis of 3-benzyl-2-phenylthiazolidin-4-one (47, Fig. 21) demonstrates the mercaptane scavenging applicability of the aminoethanethiol resin (48). Benzaldehyde is allowed to react with benzylamine in the presence of mercapto acetic acid (49) in toluene under refluxing conditions. 

Triphenylmethanol treated with 0.55 eqs. of Lawesson s reagent in DME at room temp, under argon for 15 h (or in toluene under reflux for ca. 10 min) triphenyl-methanethiol. Y 100%. Reaction of tert. alcohols possessing an alkyl group at the a-position led to alkene formation (especially in refluxing toluene), but thiol formation predominated at lower temp. F.e. [of sec. and tert. benzylic or allylic mercaptans] s. T. Nishio, J. Chem. Soc. Chem. Commun. 1989, 205-6. 

---