Titanium suboxides

Titanium silicalite Titanium silicates Titanium-silicon alloy Titanium slag Titanium suboxides... 

Jin, S.H., et ah, Conformal coating of titanium suboxide on carbon nanotube networks by atomic layer deposition for inverted organic photovoltaic cells. Carbon, 2012. 50(12) p. 4483-4488. 

The materials which are conunonly used for the anode are graphite (carbon), Pt Au, Ti coated by Pt (Pt/Ti), Rh/Ti, Ti027Ti, Ru027Ti, Pb02/Pb, some types of alloy of Pb (Pb-Ag, Pb-Sb) and titanium suboxide. 

Rupprechter G, Seeber G, GoUer H, Hayek K (1999) Structme-activity correlations on Rh/ AljOj and Rh/TiO thin film model catalysts after oxidation and reduction. J Catal 186 201 Haerudin H, Bertel S, Kramer R (1998) Surface stoichiometry of titanium suboxide, part I volumetric and FTIR study. J Chem Soc Faraday Trans 94 1481... 

On the other hand, catalytic effects of this surface titanium suboxide are not so clear. There is evidence in the literature (2) and in this Symposium (1JD that geometric effects are dominant in Pt. But in the case of Ni, the bonding of CO and H2 is altered (6, 11). Sachtler (12) suggested that the oxophilic nature of reduced titanium may weaken the C-0 bond upon CO chemisorption near such sites. If this is true, other oxophilic ions should show similar characteristics. In this paper, we report Auger and EELS studies of Ni/MnOx model catalysts prepared by vacuum evaporation of Ni onto an oxidized manganese foil and subsequent reduction at 500 K. 

The equilibrium and surface segregation calculations support the view that the SMSI effects in Pt/Ti02 catalysts are due to a monolayer (or less) of strongly-adsorbed titanium suboxide on the platinum surface. 

TiO - covered Pt tip. In that case, it was observed that as the temperature was increased, the migration of titanium suboxide initially occurred over (100) and (110) planes, leaving (111) planes uncovered. At higher temperatures, a more massive transport of titanium oxide occurred, covering all the planes. 

H. Haemdin, S. Bertel, R. Kramer, Surface stoichiometry of titanium suboxide -Part I-Volumetric and FTIR study, J. Chem. Soc., Faraday Trans. 1998, 94(10), 1481-1487. 

Ebonex. Titanium suboxide material for electrodes for electrochemistry, and for use as a high temperature lubricant. Specific properties depend on the proportions of suboxides present. See... 

The Ti02 flakes can be reduced to titanium suboxides yielding a dark bluish mass tone in addition to the interference color. ... 

In 2009, Atraverda achieved a bipolar element, Ebonex , that meets the bipolar design requirements by combining Ebonex powder with thermoset resins and lead alloy foil. Ebonex powder is a titanium suboxide material that has an electrical conductivity comparable to that of carbon and a high oxidation resistance. The Ebonex is a bipole element that serves as both the support structure and divider for the positive and negative electrode paste material. 

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