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Titania water solvent

Figure 4 shows a similar phenomenon as that originally observed in nonaqueous or nearly nonaqueous solvents. The addition of titania enhances the conductance of a solution of phosphoric acid in alcohol-rich mixed methanol-water solvent, and at sufficiently high acid concentration, the conductometric curve of the dispersion is roughly parallel to the original conductometric curve of the solution. The distance between the parallel lines representing the dispersion on the... [Pg.58]

The addition of titania depresses the conductance of solutions of oxalic acid in water-rich mixed ethanol-water solvent. Qualitatively similar effects were observed in solutions of oxalic and phosphoric acids in water-rich mixed methanol-water and ethanol-water solvents. It should be emphasized, that there is no sharp transition from water-like... [Pg.59]

Titania and silica glass thin films Au, Pt Photoreduction of HAuCl and K.2PtCl4 in ethanol-water in the presence of poly(N-vinyl-2-pyrrolidone) or poly(methyl vinyl ether led to metal particles (sizes depended on solvent composition the smallest, 2.8 nm in diameter, was obtained in 100% alcohol) which were mixed with Ti(i-OC3H7)4 and acetylacetone under N2. Subsequent to 30 minutes of stirring, exposure to moisture produced Ti02-embedded metal particles 74... [Pg.214]

The solid residue of ammonium chloride left after evaporation of the solvent water decomposes to gaseous HC1 and NH3 during the baking. Anti-reflective coatings (e.g., of alumina or titania) may also be applied by sol-gel methodology. [Pg.419]

The type of mesostructure obtained depends strongly on the surfactant to inorganic ratio. In fact, there is a close correlation between the surfactant to solvent ratio in the phase diagram of a surfactant and the surfactant to inorganic ratio in the mesostructured materials obtained. Alberius et al. demonstrated this correlation by the so-called general predictive synthesis approach. They used the phase diagrams of the water-surfactant system to guide the synthesis of mesoporous silica and titania films. There was a very close correlation between the values of the volume fraction of the surfactant over which different phases are obtained in the water-surfactant system and in the silica-surfactant and titania-surfactant systems. [Pg.1832]

Alumina was studied in aqueous alcohols [925], aqueous dioxane [666,963], aqueous dimethylsulfoxide (DMSO), aqueous glycerol, and aqueous heavy water [963]. Fe2O3 was studied in aqueous alcohols [1375,1386,1434,1456], aqueous dioxane [1388], and aqueous DMSO [1411]. Goethite was studied in aqueous acetone and aqueous methanol [1521]. Silica was studied in aqueous alcohols [1838, 1910,1911] and in other water-organic mixtures [1838]. Silica capillary was studied by electro-osmosis in 50 50 mixtures of organic solvents with water in the presence of a phosphate buffer [2927]. Surface charging of silica in mixed solvents is reviewed in [3110]. Titania was studied in aqueous alcohols [220,550,1986, 1988,2059,2115], aqueous dioxane [666,963], aqueous DMSO, aqueous glycerol, and aqueous heavy water [963]. Yttria was studied in aqueous alcohols [220]. [Pg.873]

Alumina and titania in different solvents were studied in [822]. MgO and ZnO in seven organic liquids were studied in [1686]. Silica in a series of nonaqueous solvents and in acetonitrile-water and methanol-water mixtures was studied in [3139,3140]. Only positive potentials are reported, probably by mistake. Silica in decane was studied in [3141]. ZnO in absolute methanol, ethanol, and propanol was studied in [3142]. Montmorillonite in 2-propanol was studied in [3143]. Silicon in a 99% l-butanol-1% water mixture was studied in [3145]. In [3146], 11 solids (oxides and inorganic salts) in 9 solvents were studied. [Pg.875]

Silica in 80-95% dioxane in the presence of HCI, KOH, and different 1 1 salts was studied in [314]. Silica in nonaqueous solvents containing 1 mass% of water in the presence of CsCl was studied in [3155]. Silica in methanol in the presence of KCl was studied in [282]. Quartz in DMSO in the presence of various 1-1 electrolytes was studied in [3156]. Quartz in ethanol in the presence of various 1-1 electrolytes was studied in [3157,3158]. Quartz in DMSO, acetone, and 1-butanol in the presence of NaBr or LiBr was studied in [3151]. Silica in methanol, acetonitrile, and methanol-water mixtures, with or without NaCl was studied in [1853]. Silica in 99.7% acetone in the presence of Nal and BU4NI was studied in [1908]. Titania in different 99% organic-1% water mixtures in the presence of CsCl and other 1-1 salts was studied in [3160]. Anatase in different organic solvents in the presence of CsOH and HCIO4 was studied in [3161].Titania in -alcohols in the presence of different salts was studied in [2037]. LIF, Cal 2, and MgF, in methanol, acetone, and nitroethane in the presence of NaF were studied in [3162]. Agl in ethanol at concentrations of LiNQ, up to 0.01 M was studied in [3163]. ("aSiO, in DMSO at different concentrations of NaBr and CaBr2 was studied in [3144]. Diamond in 96% ethanol in the presence of various 1-1 salts was studied in [3164]. [Pg.876]

FIGURE 49 The influence of the mesoporosity of the catalyst on its activity and on the polymer melt index and MW. Cr/silica-titania hydrogel (450 m2g ) was dried by first replacing the pore water with a solvent of varying surface tension to produce catalysts having a variety of pore volumes that were then activated at 800 °C and tested at 105 °C. [Pg.235]

The properties of the deposited Ti02 layer, such as thickness, uniformity, and crystallinity, can be tailored using different solvents such as water, ethanol, or a mixture therefrom. The addition of poly(vinyl pyrroli-done) to the solvents prevents the aggregation of the Ti02 nanoparticles. The titania layer on the parylene film is stable and cannot be removed by a simple washing procedure with water, ethanol, or acetone. [Pg.57]

One of the most troublesome aspects of water-based slip development is the high dielectric constant of the "universal solvent," which, after a few steps of logic, which we ll exclude to give you a puzzle to ponder, leads to the point that water-based slip formulations tend to be aggressively powder dependent. Where a PVB slip might be useful for alumina, zirconia, titania, ferrite, and nickel metal, a water-based slip will tend to work only for one certain powder chemistry and fail miserably for other similar powders. [Pg.225]


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See also in sourсe #XX -- [ Pg.330 ]




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