Thorium—continued

Rutherford and Owens decided that thorium continuously emitted a gaseous radioactive substance, which they called the emanation (from the Latin to flow) of thorium, or thoron. 

Uranium and thorium are the first members of natural radioactive chain which makes their determination in natural materials interesting from geochemical and radioecological aspect. They are quantitatively determined as elements by spectrophotometric method and/or their radioisotopes by alpha spectrometry. It is necessary to develop inexpensive, rapid and sensitive methods for the routine researches because of continuous monitoring of the radioactivity level. 

Thermionic Emission - Because of. the nonzero temperature of the cathode, free electrons are continuously bouncing inside. Some of these have sufficient energy to overcome the work function of the material and can be found in the vicinity of the surface. The cathode may be heated to increase this emission. Also to enhance this effect, cathodes are usually made of, or coated with, a low work-function material such as thorium. 

Spectral Gamma Ray Log. This log makes use of a very efficient tool that records the individual response to the different radioactive minerals. These minerals include potassium-40 and the elements in the uranium family as well as those in the thorium family. The GR spectrum emitted by each element is made up of easily identifiable lines. As the result of the Compton effect, the counter records a continuous spectrum. The presence of potassium, uranium and thorium can be quantitatively evaluated only with the help of a computer that calculates in real time the amounts present. The counter consists of a crystal optically coupled to a photomultiplier. The radiation level is measured in several energy windows. 

Resonance ionization methods (RIMS) have also been explored for improving Th ionization efficiency for mass spectrometric measurement (Johnson and Fearey 1993). As shown in Figure 3, two lasers are required, a continuous resonant dye laser for resonance of thorium atoms, and a continuous UV argon laser for transition from resonance to ionization. Consequently, sophisticated laser instrumentation is required for these methods. 

Johnson SG, Fearey BL (1993) Spectroscopic study of thorium using continuous-wave resonance ionization mass-spectrometry with rrltraviolet ionization. Spectrochim Acta Part B 48 1065-1077 Knoll GF (1989) Radiation Detection and Measurement. J. Wiley and Sons, New York Kuss HM (1992) Applications of microwave digestion technique for elemental analyses. Fresenins J Anal Chem 343 788-793... 

This very long half-life (1.25x1(r years) isotope comprises 0.0117 percent of all potassium. Thus, this isotope is present in all of us and has always been so. In addition, the materials around us, including the soil and the building materials, contain both potassium and the heavy naturally occurring radioactive elements thorium and uranium that contribute to a level of radiation to which we are all continuously exposed. Thus, there is always radiation exposure to the general public and we must understand the exposure due to radon in this context. The amount of radioactivity is described in units of activity. The activity is the number of decay events per unit time and is calculated as follows... 

Bacon and Anderson [42] determined 230thorium and 228thorium concentrations, in both dissolved and particulate forms, in seawater samples from the eastern equatorial Pacific. The results indicate that the thorium isotopes in the deep ocean are continuously exchanged between seawater and particle surfaces. The estimated rate of exchange is fast compared with the removal rate of the particulate matter, suggesting that the particle surfaces are nearly in equilibrium with respect to the exchange of metals with seawater. 

Black body radiators are used as sources of infrared radiation in the range 2-15 yum, e.g. the Nemst glower, which consists of a hollow rod made of the fused oxides of zirconium, yttrium and thorium. For use it is preheated and, when a voltage is applied, it emits intense continuous infrared radiation with very little visible radiation. 

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