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Thiophenols amino

Regarding the substituent effect on reactivity of groups in positions 4 and 5 there is little information in the literature. The reactivity of halogen in position 5 seems to be increased when an amino group is present in position 2. Substitution products are easily obtained using neutral nucleophiles such as thiourea, thiophenols, and mercaptans (52-59). [Pg.572]

Although phenols have not participated in the Conrad-Limpach reaction under certain conditions thiophenols were not as innocent. Lee and coworkers reported mixtures of thiochromenones and quinolones from reactions of amino-thiophenols with ethyl benzoyl acetate. Amino-thiophenol 67 reacted with ethyl benzoylacetate 68 in PPA to give a mixture of thiochromenone 70 and quinolone 69 in which the quinolone predominated. [Pg.405]

Reactions between aziridine-2-carboxylic acids and thiols in aqueous solution have been explored by Hata and Watanabe [112]. The reactions occurred predominantly at C-2 instead of C-3 to afford 3-amino acids, with the reaction between 148 (Scheme 3.53) and thiophenol in 0.2 m sodium phosphate buffer at room tem-... [Pg.94]

Benzenesulfonyl chloride, 4-methyl- [p-Tol-uenesulfonyl chloride], 55, 57, 59 Benzenethiol [Phenol, thio-], 55, 122 Benzenethiol, copper(I) salt [Thiophenol, copper(I) salt], 55, 123 Benzenethiol, lithium salt [Thiophenol, lithium salt], 55, 1 22 Benzoic acid, 2-amino- [Anthramlic acid], p bromination of, 55, 23... [Pg.145]

Phenyl-thiocyanat kann in alkoholischcr 2 n Schwefelsaure in Thiophenol iiberfiihrt werden (Blei-Kathode). (Nitro-phenyl)-cyan-sulfide ergeben neben etwas Amino-thio-phenol iiberwiegend dimere und heterocyclische Verbindungen (s. S. 687) ... [Pg.635]

In alkoholischer 2 n Sehwefelsaure werden neben 4-Amino-thiophenol hauptsachlich Dimere und Heterocyc-len erhalten F. Fighter u. F. Beck, B. 44, 3636 (1911). [Pg.685]

Herz A process for making o-amino thiophenols by heating the hydrochlorides of aromatic amines with sulfur monochloride at 50 to 75°C. The products are used as intermediates in the manufacture of thio-indigo dyestuffs. Invented by R. Hertz in Germany in 1914. [Pg.127]

I.2 Pyrrolo-benzothiazepines with other fusion modes. Thiazepine with fused pyrrole ring 250b can be prepared by condensing ortho-amino thiophenol with pyrrole carbaldehyde 249 in moderate yield (Equation (31), Section 3.1.1.4... [Pg.46]

The addition of anilines to styrene oxide was reported to also proceed in the presence of 10mol% 37 affording the corresponding P-amino alcohols 1-5 in yields ranging from 75% to 92% (Scheme 6.37). Additionally, urea derivative 37 (20mol% loading) was found to catalyze the addition of aniline (2.0 equiv.) to ( )-stilbene oxide (92% yield 5.9 d 30°C), the addition of thiophenol (2.0 equiv.) to 2-methoxy styrene oxide (85% 20h rt), and the alcoholysis of 4-methoxy styrene oxide with benzyl alcohol (2.0 equiv.) affording the respective P-alkoxy alcohol (82% 20h rt). [Pg.183]

Methylene-substituted tetrahydro-l,3-oxazine 141 underwent ring opening in response to nucleophilic attack by carboxylic acids or thiophenols to afford the A -acetyl derivatives of the corresponding 0-acyl-l,3-amino alcohols 168 or aminoalkyl sulfides 169 in high yields (Scheme 27) <2006JC0262>. [Pg.397]

Arylazo-Derivate von Chinoxalin, 1,4-Benzothiazin und 1,4-Benzoxazin sind durch Re-aktion von Phenylhydrazono-acetylchlorid mit 1,2-Diamino-benzol, 2-Amino-phenol und 2-Amino-thiophenol zuganglich. Die zunachst gebildeten Hydrazone konnen mit Wasser-stoffperoxid leicht zu den Arylazo-Verbindungen oxidiert werden. Die Ausbeuten fur beide Schritte sind annahernd quantitativ2 ... [Pg.87]

Die photochemisehe Addition von 2-Amino-thiophenol an Cyclohexen fuhrt nicht zu einem 1,4-Thiazin-Derivat, sondern zu einem spirocyclischen S,N-Acetal2. [Pg.811]

The lower members of the homologous series of 1. Alcohols 2. Aldehydes 3. Ketones 4. Acids 5. Esters 6. Phenols 7. Anhydrides 8. Amines 9. Nitriles 10. Polyhydroxy phenols 1. Polybasic acids and hydro-oxy acids. 2. Glycols, poly-hydric alcohols, polyhydroxy aldehydes and ketones (sugars) 3. Some amides, ammo acids, di-and polyamino compounds, amino alcohols 4. Sulphonic acids 5. Sulphinic acids 6. Salts 1. Acids 2. Phenols 3. Imides 4. Some primary and secondary nitro compounds oximes 5. Mercaptans and thiophenols 6. Sulphonic acids, sulphinic acids, sulphuric acids, and sul-phonamides 7. Some diketones and (3-keto esters 1. Primary amines 2. Secondary aliphatic and aryl-alkyl amines 3. Aliphatic and some aryl-alkyl tertiary amines 4. Hydrazines 1. Unsaturated hydrocarbons 2. Some poly-alkylated aromatic hydrocarbons 3. Alcohols 4. Aldehydes 5. Ketones 6. Esters 7. Anhydrides 8. Ethers and acetals 9. Lactones 10. Acyl halides 1. Saturated aliphatic hydrocarbons Cyclic paraffin hydrocarbons 3. Aromatic hydrocarbons 4. Halogen derivatives of 1, 2 and 3 5. Diaryl ethers 1. Nitro compounds (tertiary) 2. Amides and derivatives of aldehydes and ketones 3. Nitriles 4. Negatively substituted amines 5. Nitroso, azo, hy-drazo, and other intermediate reduction products of nitro com-pounds 6. Sulphones, sul-phonamides of secondary amines, sulphides, sulphates and other Sulphur compounds... [Pg.1052]


See other pages where Thiophenols amino is mentioned: [Pg.151]    [Pg.164]    [Pg.76]    [Pg.247]    [Pg.132]    [Pg.103]    [Pg.301]    [Pg.274]    [Pg.310]    [Pg.440]    [Pg.245]    [Pg.117]    [Pg.82]    [Pg.138]    [Pg.377]    [Pg.234]    [Pg.240]    [Pg.240]    [Pg.118]    [Pg.41]    [Pg.105]    [Pg.201]    [Pg.118]    [Pg.1512]    [Pg.264]    [Pg.880]    [Pg.164]    [Pg.1028]    [Pg.545]    [Pg.19]    [Pg.722]    [Pg.847]    [Pg.973]    [Pg.184]    [Pg.154]   
See also in sourсe #XX -- [ Pg.633 , Pg.634 ]




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2- Amino thiophenol

4- thiophenolates

Ortho-amino thiophenols

Thiophenolate

Thiophenols

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