Thermodynamics of Hydrogen Bonding

Henry M. 2002. Thermodynamics of hydrogen bond patterns in supramolecular assemblies of water molecules. ChemPhys Chem 3 607-616. 

The University of Gdansk, Poland, has played a crucial role in my teaching and research on the thermodynamics of hydrogen bonding in nonaqueous solvents and engine oils physicochemistry, where I was Professor of Chemistry until 1990. 

DiPaola-Baranyi, G. Guillet J. E. Jeberien, H. -E. Klein, J. E., "Thermodynamic of Hydrogen Bonding Polymer-Solute Interactions by Inverse Gas Chromatography," Makromol. Chem., 181, 215 (1980). 

The experimental determination of Aff and AS sometimes yields surprising results, as, for example, in the thermodynamics of hydrogen-bond formation in the complex of FK506 or rapamycin with FK506-binding protein (FKBP). " Binding to the wild-type and to the mutant Tyr 82 Phe 82 was... 

In order to determine to what extent these speculations have validity, it is necessary to be able to evaluate more quantitatively the relative contributions of these interactions to the free energies of protein and nucleic acid molecules in water and nonaqueous solvents. For this purpose, a substantial body of quantitative data is required concerning the properties of suitable model compounds in a variety of solvents, including their solubilities, acid-base dissociation constants, and thermodynamics of hydrogen bond formation. The dearth of pertinent data on hydrogen bonds in solvents of interest is particularly frustrating to even a semiquantitative evaluation of the scheme presented in Fig. 7. 

The thermodynamics of hydrogen bonding can be described in terms of the Helmholtz energy ... 

In view of the current interest in highly sterically hindered aryl phosphorus compounds the report of dipole moment studies of trimesityl- and triphenyl-phosphine oxides is worth noting. The thermodynamics of hydrogen-bonded complexes of triphenylphosphine oxide and various alkylarylphosphine oxides with a number of hydroxyl-containing compounds have been studied. 

Ross PD, Rekharsky MV, Thermodynamics of hydrogen bond and hydrophobic interactions in cyclodextrin complexes, Biophys. J. 1996 71 2144-2154. 

Since not much information was available on the quantitative thermodynamics of hydrogen bonding involving the N—H bonds of secondary amides, Bhaskar and Rao (1967) carried out investigations on the self-association of secondary amides as well as their interaction with certain bases by infrared spectroscopy. They studied the thermodynamics of the hydrogen-bonding interaction of cis as well as irons N—H bonds of secondary amides. 

Ikonomou, G.D., and Donohue, M.D. (1986) Thermodynamics of hydrogen-bonded molecules the associated perturbed anisotropic chain theory, AJChEJ. 32, 1716-1725. 

Molecular Thermodynamics of Hydrogen-Bonded Systems where... 

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