Thermodynamic properties Debye-Hiickel parameter

Helgeson, H. C. and D. H. Kirkham, 1974, Theoretical prediction of the thermodynamic behavior of aqueous electrolytes at high pressures and temperatures, II. Debye-Hiickel parameters for activity coefficients and relative partial molal properties. American Journal of Science 274, 1199-1261. 

BRA/PIT] Bradley, D. J., Pitzer, K. S., Thermodynamics of electrolytes. 12. Dielectric properties of water and Debye-Hiickel parameters to 350°C and 1 kbar, J. Phys. Chem., 83, (1979), 1599-1603. Cited on page 451. 

This 268 page article is concerned with the prediction of the thermodynamic properties of aqueous electrolyte solutions at high temperatures and pressures. There is an extensive discussion of the fundamental thermodynamics of. solutions and a discussion of theoretical concepts and models which have been used to describe electrolyte solutions. There is a very extensive bibliography ( 600 citations) which contains valuable references to specific systems of interest. Some specific tables of interest to this bibliography contain Debye-Hiickel parameters at 25 C, standard state partial molar entropies and heat capacities at 25 °C, and parameters for calculating activity coefficients, osmotic coefficients, relative apparent and partial molar enthalpies, heat capacities, and volumes at 25 °C. 

The beginning of the twentieth century also marked a continuation of studies of the structure and properties of electrolyte solution and of the electrode-electrolyte interface. In 1907, Gilbert Newton Lewis (1875-1946) introduced the notion of thermodynamic activity, which proved to be extremally valuable for the description of properties of solutions of strong electrolytes. In 1923, Peter Debye (1884-1966 Nobel prize, 1936) and Erich Hiickel (1896-1981) developed their theory of strong electrolyte solutions, which for the first time allowed calculation of a hitherto purely empiric parameter—the mean activity coefficients of ions in solutions. 

---