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Thermodynamic partial derivatives evaluation

The procedure would then require calculation of (2m+2) partial derivatives per iteration, requiring 2m+2 evaluations of the thermodynamic functions per iteration. Since the computation effort is essentially proportional to the number of evaluations, this form of iteration is excessively expensive, even if it converges rapidly. Fortunately, simpler forms exist that are almost always much more efficient in application. [Pg.117]

Actually, the various equations listed in this section are insufficient to perform the complete calculation since one would first calculate the density of H2O through eq. 8.12 or 8.14. Equation 8.14 in its turn involves the partial derivative of the Helmholtz free energy function 8.15. Moreover, the evaluation of electrostatic properties of the solvent and of the Bom functions (o, Q, Y, X involve additional equations and variables not given here for the sake of brevity (eqs. 36, 40 to 44, 49 to 52 and tables 1 to 3 in Johnson et ah, 1991). In spite of this fact, the decision to outline here briefly the HKF model rests on its paramount importance in geochemistry. Moreover, most of the listed thermodynamic parameters have an intrinsic validity that transcends the model itself... [Pg.538]

Application to Macromolecular Interactions. Chun describes how one can analyze the thermodynamics of a particular biological system as well as the thermal transition taking place. Briefly, it is necessary to extrapolate thermodynamic parameters over a broad temperature range. Enthalpy, entropy, and heat capacity terms are evaluated as partial derivatives of the Gibbs free energy function defined by Helmholtz-Kelvin s expression, assuming that the heat capacities integral is a continuous function. [Pg.366]

I. G. Murgulescu and L. Marta. Rev. Roumalne Chim. 457 (1966). The authors adopted total vapor pressures reported by Wartenberg and Albrecht, loc. dt.. for the evaluation of the partial pressures of KBr(g) and K2Br2(g). We use the KBr partial pressures derived from JANAF table thermodynamic functions for evaluation. [Pg.438]

When taking these partial derivatives it must be remembered that, in general, the molar densities, the mass transfer coefficients, and thermodynamic properties are functions of temperature, pressure, and composition. In addition, H is a function of the molar fluxes. We have ignored most of these dependencies in deriving the expressions given above. The important exception is the dependence of the K values on temperature and composition that cannot be ignored. The derivatives of the K values with respect to the vapor mole fractions are zero in this case since the model used to evaluate the K values is independent of the vapor composition. [Pg.288]

Newton s method requires the evaluation of the partial derivatives of all equations with respect to all variables. The partial derivatives of thermodynamic properties with respect to temperature, pressure, and composition are most awkward to obtain (and the ones that have the most influence on the rate of convergence). Since pressure is an unknown variable in this model, the derivatives of K values and enthalpies with respect to pressure must be evaluated. Neglect of these derivatives (even though they are often small) can lead to convergence difficulties. [Pg.406]

The fundamental problem in classical equilibrium statistical mechanics is to evaluate the partition function. Once this is done, we can calculate all the thermodynamic quantities, as these are typically first and second partial derivatives of the partition function. Except for very simple model systems, this is an unsolved problem. In the theory of gases and liquids, the partition function is rarely mentioned. The reason for this is that the evaluation of the partition function can be replaced by the evaluation of the grand canonical correlation functions. Using this approach, and the assumption that the potential energy of the system can be written as a sum of pair potentials, the evaluation of the partition function is equivalent to the calculation of... [Pg.454]

Be able to evaluate the partial derivative of a thermodynamic variable with respect to one variable (e.g., temperature) while holding a second variable constant (e.g., pressure) (Sec. 6.2)... [Pg.239]

In principle, Equations 4-14 and 4-15 could be used to determine the relationship between the cross-term diffusion coefficients, although the thermodynamic information necessary to evaluate the partial derivative of chemical potential with concentration is usually not available. [Pg.62]

The thermodynamic potentials, being a system s state functions of the corresponding (natural) parameters, arc of special importance in the system state description, their partial derivatives being the parameters of the system as well. The equalities between th( second mixed derivatives are a property of the state functions and lead to relation-ship.s between the system parameters (the Gibbs-Helmholtz equations). Hence, once any thermodynamic potential (usually, the Gibbs or the Helmholtz one) has been evaluated, by means of either simulation or experiment, this means the complete characterization of the thermodynamic properties of the system. [Pg.103]

Our analysis using standard state values implies dP = 0, and under that constraint, the second term in Equation 6.44 is zero. The remaining partial derivative is the constant-pressure heat capacity of the fth substance, Cp. To evaluate the enthalpy (or other thermodynamic state functions) at a temperature, call it T2, different from a temperature Ti for which there are known enthalpies, we invoke Hess s law, treating the temperature changes of reactants and products as reaction steps. Here is an example ... [Pg.147]

As the oxygen partial pressure ratio, and hence A/u0, is known, the ambipolar conductivity is readily determined from the flux. This knowledge can be further used to calculate the partial conductivities, and by knowing Ef from the transient (i.e., by also evaluating the delay time231) to derive the thermodynamic factor (i.e., the chemical capacitance). [Pg.100]

The preceding derivations are given in more detail by Marek and Standart (5) and are applied by Marek (4) to several binary systems. The terms and 02 are evaluated from partial molal volume data or approximated from generalized correlations. According to Marek and Standart, the products and T2y2 must satisfy all criteria of thermodynamic consistency, as should yi and y2 for nonassociating systems. [Pg.149]

In Section 14.3 we showed how to evaluate K from calorimetric data on the pnre reactants and products. Occasionally, these thermodynamic data may not be available for a specific reaction, or a quick estimate of the value of K may suffice. In these cases we can evaluate the equilibrium constant from measurements made directly on the reaction mixture. If we can measure the equilibrium partial pressures of all the reactants and products, we can calculate the equilibrium constant by writing the eqnilibrinm expression and substituting the experimental values (in atmospheres) into it. In many cases it is not practical to measnre directly the equilibrium partial pressure of each separate reactant and prodnct. Nonetheless, the equilibrium constant can usually be derived from other available data, although the determination is less direct. We illustrate the method in the following two examples. [Pg.591]

The total vapour pressure of selenium in equilibrium with a mixture of Au(cr) and a-AuSe was measured in the temperature range 505 to 602 K using the Knudsen effusion method in [71RAB/RAU]. The result is presented as the partial pressure of Sc2(g) at equilibrium and the enthalpy of formation and entropy at 298.15 were evaluated to be Af//°(AuSe, a, 298.15 K) = -7.9 kJ-moP and S°(AuSe, a, 298.15 K) = 80.8 J K -moP, respectively. However, Sc2(g) is not the major species in the gas phase at the temperatures and total pressures of the study, and it is not clearly stated how the partial pressure was derived from the experiments. The result is therefore questionable and impossible to re-evaluate using the selected thermodynamic properties of the gaseous selenium species. No values were selected by the review. [Pg.308]

The vapour pressure measurements gave an enthalpy of reaction Af// (1300 K) = (259.6 4.0) kJ-mol" for the reaction WSc2(cr) W(cr) + Sc2(g). This value does not agree with the partial pressures given in Table 2 of the paper. The review re-evaluated the data and derived the thermodynamic properties of WSe2(cr) at... [Pg.559]

In order to close these expressions for particulate pressures, we also need equations for the variance of total particle volume concentration in an assemblage of particles belonging to the two different types. For an arbitrary polydisperse particulate pseudo-gas, variances of partial volume concentrations for different particles can be evaluated on the basis of the thermodynamical theory of fluctuations. According to this theory, these variances are expressible in terms of the minors of a matrix that consists of the cross derivatives of the chemical potentials for particles of different species over the partial number concentrations of such particles [39]. For a binary pseudo-gas, these chemical potentials can be expressed as functions of number concentrations using the statistical theory of binary hard sphere mixtures developed in reference [77]. However, such a procedure leads to a very cumbersome and inconvenient final equation for the desired variance. To simplify the matter, it has been suggested in reference [76] to ignore a slight difference between this variance and the similar quantity for a monodisperse system of spherical particles of the same volume concentration. This means that the variance under question may be approximately described by Equation 7.4 even in the case of binary mixtures. [Pg.158]


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