The Reforming Cycle

Semi-Regenerative reforming is carried out in cycles, with the following components  

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At start-up the catalyst is reduced and then carefully conditioned on-line, for example by sulphidation of the some part of the metal components.40 Vapourised naphtha feed, together with a source of hydrogen, is then passed into the process, and potentially all the reactions listed earlier start up. The exothermic reactions of hydrocracking and hydrogenolysis must be properly controlled, but carbon laydown is inevitable from the start, and the control of its early formation is crucial to the evolution of the reforming cycle. 

A second type of CRGT plant involving modification of the fuel before combustion (Cycle B3) is shown in Fig. 8.14. Now some part of the exhaust from the turbine (which contains water vapour) is recirculated to the reformer where the fuel is modified. Thus this FG/TCR cycle has an element of the semi-closed cycle plus modification of the combustion process. The chemical process involved in this cycle has been described in Section 8.5.4, but there is now no simple comparison that can be made between the FG/ TCR cycle and the basic STIG cycle, as de.scribed in Section 8.6.2.1. 

In another example Newby et al. [6] calculated a cycle with the reformer operating at comparable pressure and temperature but with a higher recycling rate of 1.7, leading to a conversion rate of a = 0.56 (this is closer to the conversion rate of Lloyd s steam/TCR cycle, a = 0.373, described in the last section). A thermal efficiency of 38.7% is claimed for this FG/TCR cycle, slightly greater than the simple CBT cycle efficiency of 35.7% but much less than the calculated efficiency for the steam/TCR cycle (48.7%) and a comparable STIG cycle (45.6%). 

The frequency of cleaning depends on the nature and concentration of the dust. Typical cleaning intervals vary from about 2 to 15 minutes. However, the cleaning action of the pulse is so effective that the dust layer may be completely removed from the surface of the fabric. Consequently, the fabric itself must serve as the principal filter media for a substantial part of the filtration cycle, which decreases cleaning efficiency. Because of this, woven fabrics are unsuitable for use in these devices and felt-type fabrics are used instead. With felt filters, although the bulk of the dust is still removed, an adequate level of dust collection is provided by the fabric until the dust layer reforms. 

In this study, an integrated methanol reformer including an evaporator and a combustor was fabricated and tested. Previous tests of the reformer with a number of on-off cycles revealed that non-uniform temperature distribution caused hot spots within the combustion plate, resulting in cracking of the welded region of the reformer. Therefore, emphasis was made to achieve a uniform temperature distribution within the reformer. In addition, start-up characteristics of the complete reforming system were investigated. 

The initiation step in the chain oxidation, reaction (43), is not affected by the presence of oxygen. SO4 radicals formed in (43) give arsenic(fV), reaction (45), initiating the following propagation cycle which leads to the reformation of As(IV)... 

Several studies were performed in order to establish the mechaiusm (5-7). The currently accepted mechartism, presented in Scheme 26.1 for the Pd(BINAP) catalyzed amination, involves the formation of a complex, Pd(BINAP)2 from a catalyst precursor (usually Pd(OAc)2 or Pd2(dba)3) and ligand this complex lies outside the catalytic cycle and undertakes dissociation of one BINAP to form Pd(BINAP) the following steps are the oxidative addition of the aryl halide to the Pd(BINAP), reaction with amine and base, and the reductive elimination of the product to reform Pd(BlNAP). 

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