Tetralin, 6-nitro

Uses Intermediate for phthalic anhydride, naphthol, 1,4-naphthoquinone, 1,4-dihydro-naphthalene, 1,2,3,4-tetrahydronaphthalene (tetralin), decahydronaphthalene (decalin), 1-nitro-naphthalene, halogenated naphthalenes, naphthol derivatives, dyes, explosives mothballs manufacturing preparation of pesticides, fungicides, detergents and wetting agents, synthetic resins, celluloids, and lubricants synthetic tanning preservative emulsion breakers scintillation counters smokeless powders. [Pg.827]

Z)-l -Nitro-l-alkene werden in Diethylether an En-amine addiert3- u. Die Additionsreak-tion verlauft weitgehend diastereo- und enantioselektiv. Durch saure Hydrolyse kann das Amin nach der Addition abgespaltcn werden und man erhalt ein Keton. So reagiert 2-Morpholino-3,4-dihydro-naphthalin mit (Z)-2-Nitro-l-phenyl-ethen zu l-(2-Nitro-l-phe-nyl-ethyl) -2-oxo-tetralin. [Pg.241]

Als Nebenprodukt wird 3-(2-Nitro-l-phenyl-ethyl)-2-oxo-tetralin (Schmp. 127-129°) erhalten. Produkt zu Nebenprodukt entstehen im Verhaltnis 4 1. [Pg.242]

Die intramolekulare Friedel-Crafts-Reaktion von anti- bzw. jy -2-Nitro-5-phenyl-3-phe-nylthio-pentan mit Zinn(IV)-chlorid fuhrt unter Erhalt der Konfiguration zu trans- bzw. cis-5-Methyl-6-phenylthio-tetralin in 76- bzw. 70%iger Ausbeute1 ... [Pg.372]

Tetralin, 6-Nitro (6-Nitio-l, 2,3,4-Tetrahydro-naphthalene). This expl is obtained in mixt with the 5-Nitro compd (above). Its differing characteristics are mp 31.4° bp 169° at 13mm and d 1.1762g/cc at 40/40°... [Pg.568]

Butansaure 3-Hydroxy-2-phthalimido- XV/1, 253 Glyoxylsaure (8-Nitro-l-tetralyl)-E6b/1, 620 (8-N02 — tetralin + ROOC-COOR)... [Pg.988]

Tetralin 2-Methyl-2-(2-nitro-ethenyl)-l-oxo- E15/1, 1176f. (Keton + R2N-CH = CR-N02)... [Pg.1131]

Alkylbenzenes. Abstraction of benzylic hydrogen proceeds readily and was observed in the early years of dione photochemistry. Reactions of phenanthrenequinone have been reported iB,ioi,ii8,i8a,i48,i78> with toluene, o-, m- and -xylene, ethylbenzene, isopropylbenzene, cumene, pseudocumene, -cymene, f-butyltoluene, -methoxytoluene, >-nitro-toluene, diphenylmethane, thioxanthene, tetralin, collidine, and quinal-dine. Only dimers of the hydrocarbon radicals were described 148> in the reactions of diphenylmethane and thioxanthene and only phenanthrene-... [Pg.72]

Nitro-6-amino-tetralin 12 II661. 5.Nitro-2 amino-2-methyl-hydilndea... [Pg.444]

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