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Tetrakis complexes vanadium

V(IV) complexes with the formula V(R2C fc)4 (R = Me, Et) were studied by Bradley et al. 11,12, 4, 5). The ethyl complex (5) is thermally unstable and air-sensitive. The thermal instability accounts for the formation of the vanadium tris(dithio-carbamate). The tetrakis(dithiocarbamato) complex is isomorphous with 4)... [Pg.89]

N- )onor Ligands. The triplet-state X-band e.s.r. spectrum of the oxo-vanadium(iv)-chelate of tetrakis(aminomethyl)methane has been recorded for frozen aqueous-glycol solutions at 77 K. The spiro conformation of the methylene groups of this ligand ensure that the two metal centres in this dinuclear complex will have a non-parallel alignment of their -tensor axes. An analysis... [Pg.58]

See other pages where Tetrakis complexes vanadium is mentioned: [Pg.47]    [Pg.60]    [Pg.203]    [Pg.147]    [Pg.49]    [Pg.466]    [Pg.440]    [Pg.62]    [Pg.108]    [Pg.280]    [Pg.515]    [Pg.250]    [Pg.1086]    [Pg.2305]    [Pg.3290]    [Pg.298]    [Pg.558]    [Pg.250]    [Pg.456]    [Pg.456]    [Pg.735]   
See also in sourсe #XX -- [ Pg.147 ]



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Tetrakis complexes

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