Temperature Control in Chemical Microstructured Reactors

To avoid mass and heat transfer resistances in practice, the characteristic transfer time should be roughly 1 order of magnitude smaller compared to the characteristic reaction time. As the mass and heat transfer performance in microstructured reactors (MSR) is up to 2 orders of magnitude higher compared to conventional tubular reactors, the reactor performance can be considerably increased leading to the desired intensification of the process. In addition, consecutive reactions can be efficiently suppressed because of a strict control of residence time and narrow residence time distribution (discussed in Chapter 3). Elimination of transport resistances allows the reaction to achieve its chemical potential in the optimal temperature and concentration window. Therefore, fast reactions carried out in MSR show higher product selectivity and yield. 

Baier, T. and Kolb, G. (2007) Temperature control of the water gas shift reaction in microstructured reactors. Chemical Engineering Science, 62,4602-4611. 

It is widely known that radiation embrittlement behaviour of reactor pressure vessel (RPV) steels depends on various parameters such as material composition, neutron flux and irradiation temperature. Sound understanding and modelling of embrittlement mechanisms require systematic knowledge of effects of individual parameters and their synthesis on microstructural development and then mechanical properties. Most such knowledge has been obtained from single-parameter experiments using test reactor irradiation. This is because test reactor irradiation allows researchers to obtain mechanical property data together with microstructural data on materials with well-controlled chemical compositions under well-controlled irradiation conditions such as flux and temperature. Surveillance data in commercial power reactors are non-systematic in this context and relevant microstructural data are very scarce. 

Various parameters must be considered when selecting a reactor for multiphase reactions, such as the number of phases involved, the differences in the physical properties of the participating phases, the post-reaction separation, the inherent reaction nature (stoichiometry of reactants, intrinsic reaction rate, isothermal/ adiabatic conditions, etc.), the residence time required and the mass and heat transfer characteristics of the reactor For a given reaction system, the first four aspects are usually controlled to only a limited extent, if at aH, while the remainder serve as design variables to optimize reactor performance. High rates of heat and mass transfer improve effective rates and selectivities and the elimination of transport resistances, in particular for the rapid catalytic reactions, enables the reaction to achieve its chemical potential in the optimal temperature and concentration window. Transport processes can be ameliorated by greater heat exchange or interfadal surface areas and short diffusion paths. These are easily attained in microstructured reactors. 

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