Synthesis of Organic Polymers

J.6J.1 Synthesis of organic polymers 2.5.63.2 Synthesis of organometallicpolymers 2J.6.4 Natural Product Synthesis 2.5.63 Phase-transfer Catalysts... 

We then study the synthesis of organic polymers by addition reactions and condensation reactions. We examine both natural and synthetic rubber and other synthetic polymers. (25.2)... 

Bacearo A, Marx A (2010) Enzymatic synthesis of organic-polymer-grafted DNA. Chemistry 16 218-226... 

In contrast to traditional porous catalysts and mesoporous materials like MCM-41, MOFs are synthesized in one step, under relatively mild conditions, and with a high yield (up to 95%). Usually it is done by precipitation from the solution of ingredients. Like with the synthesis of organic polymers, it is important that the insoluble product is formed at the rate high enough to avoid recrystallization. 

Allcock HR. Controlled synthesis of organic-inorganic polymers that possess a backbone of phosphorus and nitrogen atoms. Makromol Chem, 1981, (Suppl 4), 3-19. 

In addition to its uses for electronic devices, silicon is a major component of silicone polymers. The silicone backbone consists of alternating silicon and oxygen atoms. The synthesis of these polymers begins with an organic chloride such as methyl chloride and an alloy of silicon and copper ... 

With this synthetic and molecular structural diversity, polyphosphazene chemistry has developed into a field that rivals many areas of organic polymer chemistry with respect to the tailored synthesis of polymers for specific experimental or technological uses. Indeed, hybrid systems are also available in which organic polymers bear phosphazene units as side groups. This is discussed in another Chapter. 

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