Synthesis of Metal-Organic Frameworks MOF

The design and synthesis of metal-organic frameworks (MOFs) has yielded a large number of solids that possess useful gas and liquid adsorption properties. In particular, highly porous structures constructures constructed from discrete... 

Stock N, Biswas S (2012) Synthesis of metal-organic frameworks (MOFs) routes to various MOF topologies, morphologies, and composites. Chem Rev 112 933-969... 

T. Fri 6ic, Towards mechanochemical synthesis of metal-organic frameworks (MOFs) from coordination polymers and lattice inclusion compounds to porous materials, in Metal-Organic Frameworks Design and Application , ed. L. R. MacGillivray, John Wiley Sons, Inc., 2010. 

Tranchemontagne DJ, Hunt JR, Yaghi OM. Room temperature synthesis of metal-organic frameworks MOF-5, MOF-74, MOF-177. Tetrahedron 2008 64 8353-7. 

Synthesis of Metal-Organic Frameworks (MOFs) in DESs... 

Some di- and tricarboxylate ligands that have been used successfully in the synthesis of metal organic frameworks mentioned in this text 1 - MOF-5, MIL-53, MIL-68, MIL-101, Sc2(02CC6H4C02)3 structures with the same topology as MOF-5, but with extended linkers 7, 8 - functionalised linkers in MOF and MIL solids 9 -FIKUST-1, MIL-100 10 MOF-177. 

Li YS, Bux H, Feldhoff A et al (2010) Controllable synthesis of metal-organic frameworks from mof nanorods to oriented mof membranes. Adv Mater 22 3322... 

In this chapter we briefly review the recent progresses in the design and synthesis of metal-organic frameworks as a new class of materials with potential for NLO application. The noncentrosymmetric MOFs, discussed herein are synthesized by using either chiral ligands or unsymmetrical ligands to assemble with suitable metal ions under hydro(solvo)thermal conditions. Additionally, incorporation of alkali or alkaline earth ions into Cd carboxylate frameworks is also an effective way to produce noncentrosymmetric MOFs. 

On the other hand, the literature on fluoride crystallization is scarce, in spite of the recent work on nanosized fluoride particles for applications in optics or catalysisInterest in fluorides is mainly driven by their properties as crystallization agents for the synthesis of zeolites or phosphate-based materials and more recently of metal organic frameworks ° (MOF). Mixed anions (fluoride-phosphate, fluoride-carboxylate...) build three-dimensional 3D open frameworks for gas storage (CO2), catalysis or emerging applications (the symbols OD, ID, 2D, 3D, characteristic of the dimensionality of the frameworks, are used throughout this chapter). 

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