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Susceptibility coefficient

The main problem of elementary chemical reaction dynamics is to find the rate constant of the transition in the reaction complex interacting with its environment. This problem, in principle, is close to the general problem of statistical mechanics of irreversible processes (see, e.g., Blum [1981], Kubo et al. [1985]) about the relaxation of initially nonequilibrium state of a particle in the presence of a reservoir (heat bath). If the particle is coupled to the reservoir weakly enough, then the properties of the latter are fully determined by the spectral characteristics of its susceptibility coefficients. [Pg.7]

The graphs in Eq. (45) are the same as occur in the susceptibility coefficients dn, but each graph is now multiplied by a mean-square length factor. Taking for the self-avoiding walk approximation simple chains C , and using the results of Section IV-C we find... [Pg.253]

Figure 17. Biaxial flexural strength, as a function of stress rate (a) and predicted flexural strength as a function of time to fracture (b) for UST dental porcelain, with and without ion exchange, in artificial saliva at 37°C. In a),(Jjo is the scaling parameter and n is the slow crack growth, SCG, susceptibility coefficient. Inert strength was determined at 100 MPa/s in air with a drop of silicone oil on the tensile surface to inhibit the occurrence of SCG. In (b), the slope of fitted curve is related with n. Data from [63,71]... Figure 17. Biaxial flexural strength, as a function of stress rate (a) and predicted flexural strength as a function of time to fracture (b) for UST dental porcelain, with and without ion exchange, in artificial saliva at 37°C. In a),(Jjo is the scaling parameter and n is the slow crack growth, SCG, susceptibility coefficient. Inert strength was determined at 100 MPa/s in air with a drop of silicone oil on the tensile surface to inhibit the occurrence of SCG. In (b), the slope of fitted curve is related with n. Data from [63,71]...
Gonzaga CC, Cesar PF, Miranda Jr WG, Yoshimura HN. Determination of the slow crack growth susceptibility coefficient of dental ceramics using different methods. Journal of Biomedical Materials Research Part B - Applied Biomaterials 2011 99(2) 247-257. [Pg.194]

Actually, it has been shown that the highest second order susceptibility coefficients (macroscopic nonlinearity), for a given chromophore (microscopic nonlinearity), can be reached in the (polar) crystal classes 1, 2, m and mm2, while other polar crystal classes are less favourable [21]. [Pg.95]

Indentation Microcracks as a Route to Stress-Corrosion Susceptibility Coefficients. 201... [Pg.175]

In equation (5.103), V is the crack velocity, Ki the stress intensity coefficient, and B and n are constants dependent on the material and its environment. The constant B is sometimes written as V to signify that it represents the critical velocity of crack growth at failure. The exponent n is an important parameter known as the stress-corrosion susceptibility coefficient of the ceramic. [Pg.275]

We have heretofore had ample discussion of linear optical properties of ZnO and related materials. In this section, the nonlinear processes in ZnO are discussed, a topic that has been investigated in some detail. The research on nonlinear optical properties of semiconductors is motivated by electro-optic devices that can be used in telecommunications and optical computing as efficient harmonic generators, optical mixers, and tunable parametric oscillators, among others. The nonlinear optical properties such as second harmonic generation (SHG), that is, (2(0i, 2(02), and the sum frequency generation (SFG), that is, (materials characterization, particularly surfaces, because the second-order susceptibility coefficient is very sensitive to the change in symmetry (178,179). The crystal should be... [Pg.212]


See other pages where Susceptibility coefficient is mentioned: [Pg.563]    [Pg.659]    [Pg.674]    [Pg.26]    [Pg.9]    [Pg.358]    [Pg.358]    [Pg.155]    [Pg.97]    [Pg.185]    [Pg.187]    [Pg.308]    [Pg.308]    [Pg.268]    [Pg.274]    [Pg.358]    [Pg.299]    [Pg.207]   
See also in sourсe #XX -- [ Pg.674 ]




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