Surface tension of the liquid

A liquid of density 2.0 g/cm forms a meniscus of shape corresponding to /3 = 80 in a metal capillary tube with which the contact angle is 30°. The capillary rise is 0.063 cm. Calculate the surface tension of the liquid and the radius of the capillary, using Table II-l. 

The uncertainties in choice of potential function and in how to approximate the surface distortion contribution combine to make the calculated surface energies of ionic crystals rather uncertain. Some results are given in Table VII-2, but comparison between the various references cited will yield major discrepancies. Experimental verification is difficult (see Section VII-5). Qualitatively, one expects the surface energy of a solid to be distinctly higher than the surface tension of the liquid and, for example, the value of 212 ergs/cm for (100)... 

For any ultrasound of frequency v, the longitudinal wavelength 7i at the surface can be calculated from Equation 19.1, in which a is the surface tension of the liquid and p is the density of the liquid. 

Edwards, Surface Tensions of the Liquid Ingredients of Plastic Propellant , Rept No ERDE-2/R/67, Waltham Abbey (Engl) (1967)... 

In bubbling, the control of the bubble diameter is a little easier. In these methods bubbles are made at an orifice or a multitude of orifices. If there is only one orifice, of radius r, and if bubble formation is slow and undisturbed, the greatest possible bubble volume is 27rry/gp] y is the surface tension of the liquid, p the difference between the densities of liquid and gas (practically equal to the density of the liquid), and g is acceleration due to gravity. Every type of agitation lowers the real bubble size. On the other hand, if there are many orifices near enough to each other, the actual bubble may be much larger than predicted by the above expression. 

A surfactant was defined in Chapter 8 as an agent, soluble or dispersible in a liquid, which reduces the surface tension of the liquid [1]. It is helpful to visualise surfactant molecules as being composed of opposing solubility tendencies. Thus, those effective in aqueous media typically contain an oil-soluble hydrocarbon-based chain (the hydrophobe) and a smaller water-solubilising moiety which may or may not confer ionic character (the hydrophile). The limitations of space do not permit a comprehensive detailed treatment of the chemistry of surfactants. The emphasis is therefore on a broad-brush discussion of the principal types of surfactant encountered in textile preparation and coloration processes. Comprehensive accounts of the chemistry and properties of surfactants are available [2-13]. A useful and lucid account of the chemistry and technology of surfactant manufacturing processes is given by Davidsohn and Milwidsky [ 14] ... 

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