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Supersonic Jet Spectroscopy of Selected D-A Molecules

Most investigations of photoinduced electron transfer have been performed in condensed phases. Much less is known about conditions that permit the occurrence of intramolecular ET in isolated (collision-free) molecular D-A systems. A powerful method for this kind of study is the supersonic jet expansion teehnique (which was originally developed by Kantrowitz and Grey in 1951 [66]) combined with laser-induced fluorescence (LIF) spectroscopy and time-of-flight mass spectrometry (TOF-MS). On the other hand, the molecular aspects of solvation can be studied by investigations of isolated gas-phase solute-solvent clusters which are formed in a supersonic jet expansion [67] (jet cooling under controlled expansion conditions [68] permits a stepwise growth of size-selected solvation clusters [69-71]). The formation of van der Waals complexes between polyatomic molecules in a supersonic jet pro-... [Pg.3078]

See other pages where Supersonic Jet Spectroscopy of Selected D-A Molecules is mentioned: [Pg.3078]    [Pg.3080]    [Pg.3082]    [Pg.3086]    [Pg.3088]    [Pg.3092]    [Pg.3094]    [Pg.3096]    [Pg.3098]    [Pg.3102]    [Pg.3078]    [Pg.3080]    [Pg.3082]    [Pg.3086]    [Pg.3088]    [Pg.3092]    [Pg.3094]    [Pg.3096]    [Pg.3098]    [Pg.3102]   


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D spectroscopy

Jet spectroscopy

Molecule spectroscopy

Supersonic

Supersonic spectroscopy

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