Sulfur dioxide elemental halogens

The arsenic and antimony pentahalides EX5 (E group 15 element As or Sb X = F or Cl) are strong, irreversible oxidants the gas AsFs has little been used, but SbCF and SbFs are commercially available, very air-sensitive liquids which are used in dry and deoxygenated dichloromethane and liquid sulfur dioxide respectively. SbCls is easier to handle than SbFs which gives the dangerous HF by reaction with moist air. Moreover, SbCls is conveniently used in dichloromethane whereas SbFs is best used in liquid SO2. On the other hand, the side products (halogenation) are more frequently encountered with SbCls than with SbFs. The redox process follows ... 

Between 400 and 430° the hydrogen pressure reaches 1 atm. The melting point (under pressure) is above 800°. Sodium hydride dissolves in fused sodium hydroxide and in fused alkali halides. It is insoluble in liquid ammonia. Water decomposes it immediately and completely to hydroxyl ion and hydrogen. Although sodium hydride is said to be stable in dry oxygen to 230°, traces of elemental sodium present may cause its ignition at lower temperatures. Copper, lead, and iron oxides are reduced by the compound to the free metals. Sulfur dioxide, carbon monoxide, and the halogens are reduced by the hydride to dithionite, formate, and halide ions, respectively. 

Stability of oxidizers is also a concern. Halogenated products generate chlorine and bromine. Both are irritating, poisonous gases. Other materials decompose with the production of less objectionable elements or compounds. For example, the relatively stable potassium monopersulfate (Oxone), emits oxygen when it decomposes but at elevated temperatures, may also generate sulfuric acid, sulfur dioxide, or sulfur trioxide [6.3.2.3]. Small amounts of moisture (and, depending on the product, many other chemicals) reduce the stability of all oxidizers. 

The evidence that stony meteorites collected in Antarctica are weathered implies that certain chemical elements are mobilized within the affected meteorite specimens. In addition, glacial meltwater and atmospheric carbon dioxide invade the affected meteorite specimens together with halogens, sulfur-bearing componnds, and organic molecules. Therefore, meteorites that fell on the East Antarctic ice sheet are altered mineralogically as well as chemically and, for that reason, their trace-element concentrations may differ from those of non-Antarctic meteorite falls. 

Chlorine was the first halogen to be isolated as a free element. In 1774, C. W. Scheele liberated chlorine by reaction of sodium chloride, sulfuric acid, and manganese dioxide,... 

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