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Sulfones from esters

General Reaction Chemistry of Sulfonic Acids. Sulfonic acids may be used to produce sulfonic acid esters, which are derived from epoxides, olefins, alkynes, aHenes, and ketenes, as shown in Figure 1 (10). Sulfonic acids may be converted to sulfonamides via reaction with an amine in the presence of phosphoms oxychloride [10025-87-3] POCl (H)- Because sulfonic acids are generally not converted directiy to sulfonamides, the reaction most likely involves a sulfonyl chloride intermediate. Phosphoms pentachlotide [10026-13-8] and phosphoms pentabromide [7789-69-7] can be used to convert sulfonic acids to the corresponding sulfonyl haUdes (12,13). The conversion may also be accompHshed by continuous electrolysis of thiols or disulfides in the presence of aqueous HCl [7647-01-0] (14) or by direct sulfonation with chlorosulfuric acid. Sulfonyl fluorides are typically prepared by direct sulfonation with fluorosulfutic acid [7789-21-17, or by reaction of the sulfonic acid or sulfonate with fluorosulfutic acid. Halogenation of sulfonic acids, which avoids production of a sulfonyl haUde, can be achieved under oxidative halogenation conditions (15). [Pg.95]

Other Applications. Hydroxylamine-O-sulfonic acid [2950-43-8] h.2is many applications in the area of organic synthesis. The use of this material for organic transformations has been thoroughly reviewed (125,126). The preparation of the acid involves the reaction of hydroxjlamine [5470-11-1] with oleum in the presence of ammonium sulfate [7783-20-2] (127). The acid has found appHcation in the preparation of hydra2ines from amines, aUphatic amines from activated methylene compounds, aromatic amines from activated aromatic compounds, amides from esters, and oximes. It is also an important reagent in reductive deamination and specialty nitrile production. [Pg.103]

Olefins, sultones, alkanes, and alkenesulfonates may be separated by liquid chromatography on silica gel using hexane, trichloromethane-hexane, ethanol-dime thy lcarbonate, and ethanol-ammonium hydroxide as the eluents. Pueschel and Prescher [110] achieved the separation of alkene-1,4-sultone and alkene-1,3-sultone from each other and from other sulfonic acid esters in AOS by thin-layer chromatography on silica gel G with 4 1 diethylcarbonate-ligroine as the... [Pg.435]

From both economic and ecological points of view, substances derived from esters of monocarboxylic acids sulfonated in the a position form an interesting class of surfactants [1]. The general formula of these a-sulfomonocarboxylic esters, also called a-sulfo fatty acid esters or, in short, a-ester sulfonates, is Rj-CH(S03Me)-C00-R2 (with Rj and R2 = alkyl groups, Me = alkali metal). [Pg.462]

For technical applications, the production of ester sulfonates from the (purified) sulfo fatty acids involves too much effort, especially because the relevant fatty acid esters can be produced directly from the triglycerides of fats and oils by transesterification. The only possible way to produce ester sulfonates is the sulfonation of fatty acid esters. [Pg.464]

FIG. 2 Krafft points 7" of hqucous surfactant solutions vs. mixing ratio of c16/c, a-ester sulfonates. (From Ref. 58.)... [Pg.476]

Formation of Alkyl Halides from Esters of Sulfuric and Sulfonic Acids... [Pg.518]

The formation of halogenation products from Grignard reagents and sulfonic acid anhydrides is the result of an oxidative reaction pathway . This side-reaction can be reduced by using sulfonic acid esters, however, in these cases alkylations as well as twofold sulfonylations (cf. corresponding results with sulfonyl fluorides ) are competing (equations 64 and 65). [Pg.203]

Further investigation with various silyl ketene acetals is summarized in Table 6. Silyl ketene acetals derived from various esters were reacted with /V-benzyloxy-carbonylamino sulfones 1 in the presence of 0.5-1 mol% Bi(0Tf)3-4H20. The corresponding (3-amino esters 24 were obtained in moderate to good yields (Table 6). Silyl enolates derived from esters as well as thioesters reacted smoothly to give the adducts. The /V - be n z v I o x v c ar bo n v I a m i n o sulfone derived from n-butvraldehyde lp led to moderate yields of (3-amino esters when reacted with (thio)acetate-derived silyl ketene acetals (Table 6, entries 1 and 2). A very good yield was obtained when the same sulfone was subjected to a tetrasubstituted silyl ketene acetal (Table 6, entry 3). The latter afforded moderate to good yields of (3-amino esters 24 with phenylacetaldehyde, / -tolu aldehyde, and o-tolualdehyde-derived sulfones (Table 6, entries 4-6). [Pg.82]


See other pages where Sulfones from esters is mentioned: [Pg.173]    [Pg.187]    [Pg.247]    [Pg.369]    [Pg.213]    [Pg.354]    [Pg.173]    [Pg.154]    [Pg.203]    [Pg.247]    [Pg.173]    [Pg.187]    [Pg.247]    [Pg.369]    [Pg.213]    [Pg.354]    [Pg.173]    [Pg.154]    [Pg.203]    [Pg.247]    [Pg.44]    [Pg.99]    [Pg.81]    [Pg.65]    [Pg.133]    [Pg.139]    [Pg.140]    [Pg.203]    [Pg.133]    [Pg.139]    [Pg.140]    [Pg.116]    [Pg.84]    [Pg.390]    [Pg.379]    [Pg.362]    [Pg.85]    [Pg.106]    [Pg.360]    [Pg.80]    [Pg.81]    [Pg.99]   
See also in sourсe #XX -- [ Pg.1687 ]




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Alkyl sulfonate esters, from alcohols

Azides from sulfonate esters

Esters, sulfonate carbanions from

Esters, sulfonate from alcohols

Esters, sulfonate from aldehydes

From halo sulfonic acid esters

From sulfonate esters

From sulfonate esters

From sulfonates

From sulfones

Halides, alkyl from sulfonate esters

Halides, alkyl, preparation from sulfonate esters

Methyl derivatives, from sulfonate esters

Nitriles, preparation from sulfonate esters

Sulfonate ester, formation from sulfonyl

Sulfonate ester, formation from sulfonyl chloride and alcohol

Sulfonate esters

Sulfonate esters from alcohols + sulfonyl chlorides

Sulfonic acids from sulfonate esters

Sulfonic esters

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