Sulfone, benzyl phenyl crystal structure

It should be noted that the crystal structure of the Li/TMEDA salt of benzyl phenyl sulfone reported by Boche is conceptually similar to the theoretical structure (122). X-Ray structure determination of a-(phenylsulfonyl)benzyllithium-TMEDA, a-(phenylsulfonyl)allyllithium and the potassium salt of bis(methylsulfonyl)-3-(2,6-dimethyoxypyridyl)sulfonylmeAane shows that the coordination about the anionic carbon atom is nearly planar, and that the p-orbital on the anionic carbon is approximately gauche to the two oxygen atoms on the sulfur. " The anionic caibon atom can be described as interacting with the sulfur atoms in an ylide-like manner with a hairier to rotation about the "C—SO2 bond. 

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See also in sourсe #XX -- [ ]

See also in sourсe #XX -- [ ]

See also in sourсe #XX -- [ ]

See also in sourсe #XX -- [ ]

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