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Sugars spectra

Explain and assign these 100 MHz H spectra of this protected sugar. Spectrum a was obtained in dry DMSO-d6 solution b is of the same sample after addition of a trace of HC1 gas. The broken lines show the positions of changes. [Pg.61]

The similarity between the spectra of the melanoidin and the peptide is obvious. It is possible that the sugar moiety is modified substantially, which makes the melanoidin spectrum not resemble the sugar spectrum. [Pg.368]

Other methods of identification include the customary preparation of derivatives, comparisons with authentic substances whenever possible, and periodate oxidation. Lately, the application of nuclear magnetic resonance spectroscopy has provided an elegant approach to the elucidation of structures and stereochemistry of various deoxy sugars (18). Microcell techniques can provide a spectrum on 5-6 mg. of sample. The practicing chemist is frequently confronted with the problem of having on hand a few milligrams of a product whose structure is unknown. It is especially in such instances that a full appreciation of the functions of mass spectrometry can be developed. [Pg.214]

Peaks at m/e 113 and 85 have been found in the mass spectra (12) of other O-isopropylidene ketals of sugars, as well as in Figure 7. Since these shift to m/e 119 and to m/e 88 and 91 in the mass spectrum of 10a as they did for the d6-analogs in Reference 12, the structures, 17, 18, and 19 from Reference 12 are shown as possible explanations. The peak at m/e 85 (91) could alternatively be from m/e 113 (119) by loss of carbon monoxide (28 mass units) from the six-membered-ring of structure 17b. [Pg.232]

Sugar, J. [1963] Analysis of the Third Spectrum of Praseodymium , Journal of the Optical Society of America, 53, p. 831. [Pg.34]

Figure 5.31 LC-electrospray-MS-MS spectrum of the column eluate at around 22 min in the analysis of the peptide mixture from the tryptic digest of glycoprotein TIME-EA4 from silkworm diapause eggs. Reprinted from Bioorg. Med. Chem., 10, Kurahashi, T., Miyazaki, A., Murakami, Y., Suwan, S., Franz, T., Isobe, M., Tani, M. and Kai, H., Determination of a sugar chain and its linkage site on a glycoprotein TIME-EA4 from silkworm diapause eggs by means of LC-ESI-Q-TOF-MS and MS/MS , 1703-1710, Copyright (2002), with permission from Elsevier Science. Figure 5.31 LC-electrospray-MS-MS spectrum of the column eluate at around 22 min in the analysis of the peptide mixture from the tryptic digest of glycoprotein TIME-EA4 from silkworm diapause eggs. Reprinted from Bioorg. Med. Chem., 10, Kurahashi, T., Miyazaki, A., Murakami, Y., Suwan, S., Franz, T., Isobe, M., Tani, M. and Kai, H., Determination of a sugar chain and its linkage site on a glycoprotein TIME-EA4 from silkworm diapause eggs by means of LC-ESI-Q-TOF-MS and MS/MS , 1703-1710, Copyright (2002), with permission from Elsevier Science.
Many biologically important sugars are derivatives having a chromophoric group that absorbs within the range of commercial instrumentation. Not only is the c.d. spectrum of such molecules easier to measure, but the interpretation of the spectrum is simplified, because only the chromophore is involved. Many laboratories have concentrated on the c.d. of such monomers and their polymers, and the results will be discussed. [Pg.75]

However, workers do not agree as to the shape of the c.d. spectrum for these sugars at shorter wavelengths, as Fig. 15 demonstrates. The correct spectrum still remains an open question, but the intense c.d. band expected at 190 nm for the amide mr c.d. bands are of opposite sign for the two anomers and nearly cancel in the equilibrium mixture. Thus, differences in the anomeric mixtures could explain differences in the c.d. spectra. The amide irir c.d. band is obvious for the anomeric mixture from 2-acetamido-... [Pg.95]

The carboxyl chromophore is axial for the a anomer and equatorial for the p anomer. The sugar was studied as the carboxylate anion as it has a (low) piC of 2.6, and the compound is degraded in acidic solution. The c.d. spectrum of this compound contains contributions from the carboxylate n-jr at 217 nm, the amide n-tr at 210 nm, and the amide 7T7r at 190 nm. Apparently, all of these bands are positive, giving rise to a c.d. spectrum (see Fig. 29) having " a maximum at 199 nm and a shoulder at 210 nm. The c.d. spectra of a number of derivatives confirmed these assignments. [Pg.111]

Listowsky and coworkers showed that the c.d. of this sugar derivative is due entirely to lactic acid, and confirmed that this chromophore is in the D configuration for muramic acid. N-Acetylmuramic acid, in which the amino group is replaced by an amido group at C-2, has a c.d. spectrum that is roughly a linear combination of the lactic acid in muramic acid and the amide in 2-acetamido-2-deoxy-D-glucose. This indicates that the amide chromophore and the lactic acid chromophore in N-acetylmuramic acid behave independently. [Pg.113]

Acetamiprid is a neonicotinoid insecticide with outstanding systemic activities and a broad insecticidal spectrum. Acetamiprid controls diverse soil and foliar insect pests infesting cotton, sugar beet, vegetables, fruits and other major food crops by both contact and stomach action... [Pg.1242]


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See also in sourсe #XX -- [ Pg.22 , Pg.24 ]

See also in sourсe #XX -- [ Pg.624 ]




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Amino sugars mass spectra

Common sugars, spectrum

Deoxy sugars mass spectra

Nuclear magnetic resonance spectra sugars

Sugars mass spectra

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