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Subject triangular

All sources of uncertainty that are not quantified by the standard deviation of repeated measurements fall in the category of Type components. These were fully dealt with in chapter 6. For method validation, it is important to document the reasoning behind the use of Type components because Type components have the most subjective and arbitrary aspects. Which components are chosen and the rationale behind the inclusion or exclusion of components should documented. The value of the standard uncertainty and the distribution chosen (e.g., uniform, triangular, or normal) should be made available, as should the final method used to combine all sources. [Pg.255]

A trimeric complex has also been the subject of a detailed study.709 The mole ratio [Cr] [OH] was found to be 4 3 the degree of polymerization was assessed, by freezing point depression, to be three. A triangular structure, as shown in (157), was suggested on the basis of magnetic studies. [Pg.859]

A. AH2 Molecules, inclnding H3.—The simplest of these species is H, which has been the subject of a number of recent studies. Work previous to 1970 is listed by Borkman.426 The ground state is triangular (Dsn) and it has been studied using a basis set of elliptical orbitals. Contracted GTO basis sets were used in near-HF calculations by Harrison et a/.,430 and correlated wavefunctions were computed by Salmon and Poshusta,431 and by Handy.482 In the latter calculation a new form for the correlation factor was used, and the good results suggest that it might be useful for other small molecules. [Pg.134]

Obviously, only molecules with partially filled orbitals display Jahn-Teller distortion. As was shown in Section 6.3.2, the electronic ground state of molecules with completely filled orbitals is always totally symmetric, and thus cannot be degenerate. In comparison with the above-mentioned unstable H3 molecule, Hj" has only two electrons in an a symmetry orbital therefore, its electronic ground state is totally symmetric, and the D3/,-symmetry triangular structure of this ion is stable (see, e.g., Reference [62]). On the other hand, take the benzene molecule, e.g., whose ground electronic state is of Alg symmetry and the molecule is stable and its structure is well understood. At the same time, in its cation, C6Hg, it loses one electron from an c -symmetry doubly-degenerate orbital, so that orbital is left with only one electron. The electronic state of the cation has E g symmetry and thus, it is subject to Jahn-Teller effect. Indeed, its vibrational spectrum is extremely complicated and can only be satisfactory explained if the Jahn-Teller distortion is taken into consideration (see, e.g., Reference [63]). [Pg.297]

The most common bridging mode of coordination is syn-syn (47). The nature of the metal-metal interactions in such systems has been the subject of much study, with interaction varying from the relatively weak in dimeric Cu complexes, to strongly M-M bonded species such as Mo2(02CR)4, which contains a formal quadruple bond. The two systems that have been most studied are the bimetallic (52) and trimetallic (53) complexes, often referred to as paddle-wheel and triangular complexes respectively. These structural motifs have been widely utilized in the constraction of coordination polymers and metal-organic frameworks. [Pg.5068]

In one of the first articles on this subject [8], the general analytical solution of Eq. (3) was derived. This general solution is easy to find, but it contains infinite series and (integration) constants that depend on the boundary conditions. Those were determined for the central cells of square and triangular arrays, using the boundary collocation method [8]. More recent publications on this subject are based mostly on complete numerical solution using finite-element methods. [Pg.362]

To minimize II Ax - b II2 subject to the constraints Cx = d in this way, one can find a matrix K such that KC is of lower triangular form. Next form... [Pg.29]

Fig. 1. Scintillation scan of the upper abdomen of a control human subject, taken 24 hours after the intravenous administration of 1 mg radioactive labeled copper. The triangular shadow represents the liver. The dots along the curved line below the liver represent radioactive material in the second part of the duodenum. Fig. 1. Scintillation scan of the upper abdomen of a control human subject, taken 24 hours after the intravenous administration of 1 mg radioactive labeled copper. The triangular shadow represents the liver. The dots along the curved line below the liver represent radioactive material in the second part of the duodenum.
In the event of dispute, kava samples will be subject to a taste panel assessment using the triangular taste test. There will be at least 20 panelists and the results will be subjected to statistical analysis. Samples with statistically significant differences from test samples will be treated as contaminated. [Pg.41]

Inasmuch as Montroll did not report values of the coefficient A4 for triangular or hexagonal lattices, the above procedure was repeated for v = 3 and V = 6 (viz., the coefficients Ai through A3 were set at the Montroll values and A4 was determined to give the best fit of the data). The results are also given in Table III.4. These tabulations may be taken as the state of the art representation of (n) as a function of N for finite lattices m d — 1 subject to periodic boundary conditions. [Pg.264]


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