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Study 6.10 Organic synthesis copper I -catalysed photocycloaddition

Case Study 6.10 Organic synthesis - copper(I)-catalysed photocycloaddition [Pg.258]

Experimental details 11 A diethyl ether solution of the triene 115 (10.8 him) and copper(I) triflate (0.94 him) was irradiated with a medium-pressure mercury lamp [Pg.258]

Reaction media play an important role in controlling the nature of reaction pathways and therefore the reaction products and yields, and also regio- and [Pg.259]

Following pioneering work on [2 + 2] cycloadditions of cinnamic acid in crystals,714 photocycloaddition in the solid state has become another systematically investigated reaction parameter. Crystallographic studies have shown that the distance [Pg.260]




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Copper photocycloaddition

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I synthesis

Photocycloaddition synthesis

Photocycloadditions

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