Stokes cross-section

The hyperpolarizability tensor is obtained in a way similar to the case of SHG. However, the selection rules for an SFG resonance at the IR frequency implies that the vibrational mode is both IR and Raman active, as the SF hyperpolarizability tensor elements involve both an IR absorption and a Raman-anti-Stokes cross-section. Conversely, the DFG hyperpolarizability tensor elements involve an IR absorption and a Raman-Stokes cross-section. The hyperpolarizability tensor elements can be written in a rather compact form involving several vibrational excitations as [117] ... 

At Che opposite limit, where Che density Is high enough for mean free paths to be short con ared with pore diameters, the problem can be treated by continuum mechanics. In the simplest ease of a straight tube of circular cross-section, the fluid velocity field can easily be obtained by Integrating Che Nsvler-Stokes equations If an appropriate boundary condition at Che... 

The hydrauhc diameter method does not work well for laminar flow because the shape affects the flow resistance in a way that cannot be expressed as a function only of the ratio of cross-sectional area to wetted perimeter. For some shapes, the Navier-Stokes equations have been integrated to yield relations between flow rate and pressure drop. These relations may be expressed in terms of equivalent diameters Dg defined to make the relations reduce to the second form of the Hagen-Poiseulle equation, Eq. (6-36) that is, Dg (l2SQ[LL/ KAPy. Equivalent diameters are not the same as hydraulie diameters. Equivalent diameters yield the correct relation between flow rate and pressure drop when substituted into Eq. (6-36), but not Eq. (6-35) because V Q/(tiDe/4). Equivalent diameter Dg is not to be used in the friction factor and Reynolds number ... 

Porous media is typically characterized as an ensemble of channels of var ious cross sections of the same length. The Navier-Stokes equations for all chaimels passing a cross section normal to the flow can be solved to give ... 

Kfne = Proportionality factor in Stokes-Cunningham correction factor, dimensionless k = Constant for wire mesh separators 1 = Wire mesh thickness, ft L = Length of vessel from hydrocarbon inlet to hydrocarbon outlet, or length of decanter, ft L[ = Liquid entering Webre separator, lbs pel- minute per square foot of inlet pipe cross-section L, = EnLrainment from Webre unit, lb liquid per minute per square foot of inlet pipe cross section... 

Wu and Cheng (2003) measured the friction factor of laminar flow of de-ionized water in smooth silicon micro-channels of trapezoidal cross-section with hydraulic diameters in the range of 25.9 to 291.0 pm. The experimental data were found to be in agreement within 11% with an existing theoretical solution for an incompressible, fully developed, laminar flow in trapezoidal channels under the no-slip boundary condition. It is confirmed that Navier-Stokes equations are still valid for the laminar flow of de-ionized water in smooth micro-channels having hydraulic diameter as small as 25.9 pm. For smooth channels with larger hydraulic diameters of 103.4-103.4-291.0pm, transition from laminar to turbulent flow occurred at Re = 1,500-2,000. 

The estimation of f from Stokes law when the bead is similar in size to a solvent molecule represents a dubious application of a classical equation derived for a continuous medium to a molecular phenomenon. The value used for f above could be considerably in error. Hence the real test of whether or not it is justifiable to neglect the second term in Eq. (19) is to be sought in experiment. It should be remarked also that the Kirkwood-Riseman theory, including their theory of viscosity to be discussed below, has been developed on the assumption that the hydrodynamics of the molecule, like its thermodynamic interactions, are equivalent to those of a cloud distribution of independent beads. A better approximation to the actual molecule would consist of a cylinder of roughly uniform cross section bent irregularly into a random, tortuous configuration. The accuracy with which the cloud model represents the behavior of the real polymer chain can be decided at present only from analysis of experimental data. 

A number of authors have considered channel cross-sections other than rectangular [102-104]. Figure 2.17 shows some examples of cross-sections for which friction factors and Nusselt numbers were computed. In general, an analytical solution of the Navier-Stokes and the enthalpy equations in such channel geometries would be involved owing to the implementation of the wall boundary condition. For this reason, usually numerical methods are employed to study laminar flow and heat transfer in channels with arbitrary cross-sectional geometry. 

Of much greater relevance in micro reactors are rectangular channels, which were the subject of a study by Cheng et al. [110], among others. They solved the Navier-Stokes equation for channel cross-sections with an aspect ratio between 0.5 and 5 and Dean numbers between 5 and 715 using a finite-difference method. The vortex patterns obtained as a result of their computations are depicted in Figure 2.20 for two different Dean numbers. 

In this definition, ps and pt are the solid and fluid densities, respectively. The characteristic diameter of the particles is ds (which is used in calculating the projected cross-sectional area of particle in the direction of the flow in the drag law). The kinematic viscosity of the fluid is vf and y is a characteristic strain rate for the flow. In a turbulent flow, y can be approximated by l/r when ds is smaller than the Kolmogorov length scale r. (Unless the turbulence is extremely intense, this will usually be the case for fine particles.) Based on the Stokes... 

Horizontal rectangular cross-section tank. Similarly, required width and length of a horizontal tank of rectangular cross-section can be determined from Stokes Law as ... 

The critical nucleus of a new phase (Gibbs) is an activated complex (a transitory state) of a system. The motion of the system across the transitory state is the result of fluctuations and has the character of Brownian motion, in accordance with Kramers theory, and in contrast to the inertial motion in Eyring s theory of chemical reactions. The relationship between the rate (probability) of the direct and reverse processes—the growth and the decrease of the nucleus—is determined from the condition of steadiness of the equilibrium distribution, which leads to an equation of the Fourier-Fick type (heat conduction or diffusion) in a rod of variable cross-section or in a stream of variable velocity. The magnitude of the diffusion coefficient is established by comparison with the macroscopic kinetics of the change of nuclei, which does not consider fluctuations (cf. Einstein s application of Stokes law to diffusion). The steady rate of nucleus formation is calculated (the number of nuclei per cubic centimeter per second for a given supersaturation). For condensation of a vapor, the results do not differ from those of Volmer. 

For any Beltrami field, c can also be given a geometric interpretation. Calling t the unit vector along v, we apply Stokes theorem to a curve (ds) determined by an orthogonal cross section (da) of an infinitesimal circular vector tube. If r denotes the radius, we find (see Fig. 1)... 

---