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Steric effects on binding

Size Small preferred Less steric effect on binding... [Pg.362]

Table 4 Ligand Binding Site Steric Effect on CO and 02 Coordination to Fe"(For)... [Pg.831]

Selective recognition of butylamines by p-r /t-butylca-lix[6]arene ester derivatives shows the influence of steric effects on the binding strength, with z-butyl>iso-butyl- 6 c-butyl > l rl-butyl. ... [Pg.141]

The stability of olefin complexes is also sensitive to steric effects. The binding of ethylene is stronger than that of a-olefins in nearly all cases. However, the magnitude of the steric effect on the binding of an olefin depends on the other ligands. For example, the ethylene complex of bis(amine)PdMe in Equation 2.11b is 10-fold more stable than the propylene or hexene complex, while flie ethylene complex of PtClj" is ortiy two-fold more stable than the corresponding propene complex. ... [Pg.48]


See other pages where Steric effects on binding is mentioned: [Pg.797]    [Pg.225]    [Pg.608]    [Pg.608]    [Pg.797]    [Pg.225]    [Pg.608]    [Pg.608]    [Pg.107]    [Pg.36]    [Pg.378]    [Pg.136]    [Pg.162]    [Pg.112]    [Pg.28]    [Pg.264]    [Pg.36]    [Pg.2512]    [Pg.200]    [Pg.368]    [Pg.38]    [Pg.162]    [Pg.1487]    [Pg.235]    [Pg.919]    [Pg.2018]    [Pg.214]    [Pg.368]    [Pg.1323]    [Pg.22]    [Pg.579]    [Pg.111]    [Pg.292]    [Pg.225]    [Pg.50]    [Pg.87]    [Pg.211]    [Pg.277]    [Pg.310]    [Pg.77]    [Pg.67]    [Pg.165]    [Pg.17]    [Pg.245]    [Pg.81]    [Pg.193]    [Pg.77]   
See also in sourсe #XX -- [ Pg.219 ]

See also in sourсe #XX -- [ Pg.219 ]




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Binding effect

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