Stannic anhydride

Zion-saum, m. list of tin, selvedge, -allure, /. stannic acid, -saureonhydrid, n. stannic anhydride, tin dioxide, -schlich, m. (Ores) tin slimes, fine tin. -schrei, m. = 2Unngeschrei. -seife, /. (Mining) stream tin. -soda, /. sodium stannate. -staub, m. tin dust, -stein, m. tinstone, cassiterite. -sulfid, n. tin sulfide, specif, stannic sulfide, tin(IV) sulfide. -BuUocyanid, 1. tin thiocyanate, specif. 

Stannic Oxide (White Tin Oxide, Tin Dioxide, Stannic Anhydride, Flowers of Tin Stannic Acid, Cassiterite). Sn02, mw 150.69, white powd, mp 1127°, bp 1800-1900° (subl), d 6.95 g/cc. Sol in coned sulfuric and coned hydrochloric acids, si sol in hot coned aq KOH or NaOH. Prepn is by reacting Sn with coned nitric acid (d 1.41 g/cc) on a w bath forming 0-stannic acid. The 0-stannic acid is then heated to a red heat and converted to Sn02. It is used as a chemical reagent and (see above) as an antifouling, flash and barrel wear reducing additive in propints... 

Synonyms stannic oxide tin dioxide tin peroxide white tin oxide stannic anhydride flowers of tin... 

Stannic oxide. (stannic anhydride tin peroxide tin dioxide stannic acid). Sn02 or Sn()2 xl I2(). 

Stannic Oxide. White tin oxide tin dioxide stannic anhydride Bowers of tin. OjSn mol wt 150.70. O 21.23%, Sn 78.77%. Sn02. Occurs in nature as the mineral eassiterite. The commercial grade is also known as polishing powder, putty powder, or (In ash. 

Stannane, fluorolriphenyl-. SeeTriphenyltin fluoride Stannic acid Stannic anhydride. See Stannic oxide... 

CAS 1317-45-9 18282-10-5 EINECS/ELINCS 242-159-0 Synonyms Cassiterite Cl 77861 Stannic acid Stannic anhydride Stannic oxide, hydrated Tin dioxide Tin oxide (INCI) Tin oxide (ic) Tin oxide white Tin peroxide Classification Inorganic oxide Empirical OjSn OjSn nhljO... 

Octahydrodibenzothiophene (73) has been prepared by the following sequence. Friedel-Crafts acylation of 4,5,6,7-tetra-hydrobenzo[6]thiophene with succinic anhydride (87%) or with the ester chloride of succinic acid followed by hydrolysis (80%), yields the keto acid (74). Huang-Minlon reduction of 74 followed by cyclization of the derived acid chloride with stannic chloride yields l-keto-1,2,3,4,6,7,-8,9-octahydrodibenzothiophene (53) (Section V,A). Reduction of 53 gives 73 as a solid (overall yield 32%). 

Sodium toluene dispersion of, 55, 65 Sodium p-toluenesulfinate, 57, 103 Spiro[4 n] alkenones, 58, 62 Spiro[cyclopentane-l,l -indene] 55, 94 Squalene, 56, 116 Squalene, 2,3-epoxy, 56, 116 Stannic chloride, 56, 97 Steroids synthesis, 58, 85 E Stilbene, 55, 115,58, 73 z-Stilbene, 58, 133 Styrene, 56, 35,58, 43 Styrene glycol, 55, 116 Styrene glycol dimesylate, 55, 116 Succinic acid, 58, 85 Succinic anhydride, 58, 85 Sucunimide, 56, 50, 58, 126 Succimmide, Vbromo, 55, 28, 56, 49 SULFIDE CONTRACTION, 55, 127 Sulfide, dimethyl-, 56, 37 SULFIDE SYNTHESIS, 58, 143,58, 138 SULFIDE SYNTHESIS ALKYL ARYL SULFIDES, 58, 143 SULFIDE SYNTHFSIS DIALKYL SULFIDES, 58, 143 SULFIDE SYNTHESIS UNSYMMETRI-CAL DIALKYL DISULFIDES, 58, 147 SULFONYL CYANIDES, 57, 88 Sulfur tetrafluoride, 57, 51... 

Benzo[c]thiophene readily forms adducts with maleic anhydride (m.p. 153°-154°,5 6 148°-152°52), dimethyl acetylenedicarboxylate (see above),61 and A-phenylmaleimide (to give 62).52,61 In the last case the exo and endo isomers of the adduct may be separated by fractional crystallization.52 Benzo[c]thiophene reacts with acetyl nitrate by 1,3-addition in preference to substitution.6 It exhibits halochromy with concentrated sulfuric acid, trichloroacetic acid, and stannic chloride.62... 

Acetylation of pyrrole is difficult because if forms a 2 1 complex with stannic chloride (29CB226). Hence, under the conditions used for the other five-membered rings (i.e., acetic anhydride in the presence of one hundredth molar equivalent of stannic chloride or iodine), no reaction occurs, and only 20% acetylation is obtained if the molar proportion of the catalyst is reduced 10-fold. The effect of complex formation also shows up in the inhibition of stannic chloride-catalyzed acetylation of fu-ran or thiophene, on addition of pyrrole (67MI4). Catalyzed acetylation of 2-cyano-, 2-formyl-, or 2-methoxycarbonylpyrrole gives mainly 4-substitution (67CJC897) indicating that the catalyst must also be coordinated with the substrate l-methyl-3-nitropyrrole acetylates only in the 5-posi-tion (57CJC21). 

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