Standard specific gravity

T being the boiling temperature (Kelvin) and S being tbe standard specific gravity (15.6°C/15.6°C). Refer to Chapter 4. 

Group the component in a petroleum fraction, which is possible if the normal boiling temperature and the standard specific gravity are known. This method gives correct results when the chemical structure is simple as in the case of a paraffin or naphthene. 

The standard specific gravity is the ratio of the density of a hydrocarbon at 15.55°C (60°F) to that of water at the same temperature. It differs from the specific gravity d] which is the ratio of the density of a hydrocarbon at 15°C to that of water at 4°C. 

The standard specific gravity can be estimated from using the followinc relation ... 

It is common that a mixture of hydrocarbons whose boiling points are far enough apart petroleum cut) is characterized by a distillation curve and an average standard specific gravity. It is then necessary to calculate the standard specific gravity of each fraction composing the cut by using the relation below [4.8] ... 

Using the principle of corresponding states requires knowledge of pseudo-critical constants of petroleum fractions these should be estimated starting from characteristic properties which are the normal boiling temperature and the standard specific gravity. 

For petroleum fractions, the values should be calculated starting with the standard specific gravity accor( ing to the relation ... 

K y = Watson characterization factor 5 = standard specific gravity... 

Coefficients for converting an ASTM D 86 curve to an atmospheric flash curve[ and an application for a petroleum cut whose standard specific gravity isl 0.746. ... 

Calculation of the atmospheric TBP is rapid if it can be assumed that this distillation is ideal (which is not always the case in reality). It is only necessary to arrange the components in order of increasing boiling points and to accumulate the volumes determined by using the standard specific gravity. 

Within the same geographicai region, the crude specific gravity varies from one reservoir to another, in Saudi Arabia, for example, the crude from the Ghawar field has an average standard specific gravity on the order of 0.850 (34° API) while the specific gravity of the crude from the nearby Safaniyah field is 0.893 (27° API). 

Normal boiling point K Standard specific gravity Molecular weight kg/lunol Liquid viscosity at 100°F mm /s Liquid viscosity at 2iO F mm /s Critical temperature K Critical pressure bar... 

Figure 13.4. Standard specific gravity of PTFE as a function of molecular weight. (After Thomas...

Standards Engineering, 15 769 Standard-setting organizations, 9 227 Standard specific gravity (SSG) procedure, 18 293... 

A routine method for determining relative crystallinity based on the amorphous bands in the spectrum has proved more rapid and precise than the x-ray method. In practice, the ratio of the 778 cm-1 (12.85 ft) and 2367 cm-1 (4.22 ft) band intensities is measured. Use of a ratio eliminates the thickness measurement and increases precision to about 1% at 50% crystallinity and considerably better at higher levels. A density measurement and an infrared crystallinity determination when combined give an estimate of the fraction of microvoids which can occur in molded specimens of polytetrafluoroethylene. The density of a sample is predicted on the basis of its crystallinity as measured by the infrared method and the difference between this density and the actual density measured by displacement in water is a measure of the microvoid content. This determination is precise to about 0,2% voids by volume. By the use of confirmatory infrared measurements, it is possible to check the possibility that the presence of a substantial percentage of voids may have led to erroneous indications of the molecular weight in the standard specific gravity test discussed earlier. 

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