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Spin quantum number sequences

In NMR the quantum numbers I and m where I is the spin quantum number (0, 2, 1, 2,...) and m is the z-component of I with values of m = — I, — I + 1,. .., I—1,1. The spins of nuclei are given in Tables 1.1 and 1.2. The state of a nucleus would be described by the pair of quantum numbers I and m and is usually written I I,m > in Dirac bra and ket notation. This text is not intended as a primer in quantum mechanical operators but to understand papers that interpret interactions and develop new pulse sequences it is worth noting some of the most important results. [Pg.25]

From this brief discussion comparing the effect on NMR spectra of the nuclear receptivity, natural abundance and spin quantum number, all be it for a small restricted variety of NMR-active isotopes, it is obvious that it is misleading to categorize experiments into IR and heteronuclear experiments. When discussing pulse sequences. [Pg.189]

Pauli exclusion principle. A fundamental generalization concerning the energy relationships of electrons within the atom, namely that no two electrons in the same atom have the same value for all four quantum numbers corollary to this is the fact that only two electrons can occupy the same orbital, in which case they have opposite spins, i.e., +1/2 and -1/2. This principle has an important bearing on the sequence of elements in the periodic table and on the limiting numbers of electrons in the shells (2 in the first, 8 in the second, 18 in the third, 32 in the fourth, etc.). [Pg.949]

Which agrees with the result obtained using the irreducible tensor formalism.34 The triple-quantum filtration pulse sequence, applied to a spin- quadrupolar nucleus, produces almost exactly the same result as does the double-quantum filtration sequence, except for two differences. The double-quantum relaxation rate is faster than the triple-quantum relaxation rate, and the triple-quantum FID is a factor of 1.5 larger than the double-quantum FID.34 The triplequantum filter will thus require less than half the number of acquisitions to equal the signal-to-noise of the double-quantum sequence. [Pg.227]

Pauli s Exclusion Principle A pair of electrons in any suborbital must have opposite spins. Hence, no two electrons in the same atom can have the same four Quantum Numbers. To construct the electronic configuration of an atom from these rules it is necessary to know the energy levels of the different orbitak in an atom, or at least the sequence of increasing energy levels of the orbitals. [Pg.74]

Instead of using directly a sequence of quantum numbers to characterize an electronic level, the overall quantum numbers are usually expressed using a specific notation called spectroscopic terms, spectroscopic levels, and spectroscopic sublevels. A spectroscopic term P5+i)p is determined by the S and L overall quantum numbers. It defines the multiplicity of the overall spin angular momentum and represents the overall orbital quantum number as a capital letter F = S, P, D, F, G, H, etc. that corresponds to values of L =0, 1,2,3,4, 5, etc. [Pg.115]

It seems safe, therefore, to conclude that the r is indeed a new spin lepton, i.e. a point-like elementary particle whose behaviour is controlled by QED. In summary, the new lepton appears to have its own lepton quantum number, i.e. to be a sequential lepton, with its own neutrino (as is discussed later), and its spin coupling structure is consistent with the traditional V — A coupling of its lighter companions e and fi. It therefore seems to be a genuine recurrence in the g sequence. [Pg.308]


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See also in sourсe #XX -- [ Pg.97 ]




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