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Spectroscopy and Conformational Features

The influence of orbital effects on equilibrium conformation of terminally unsaturated glycenose derivatives has been calculated and compared with results obtained by H coupling constants. Glycenoses and alkenes having the general formula RCH(OR )CH=CHX E) preferentially adopt, in solution, a conformation in which the alkoxy-group eclipses the double bond. This conformation is particularly favoured by resonance when X is an electron- [Pg.187]

Alfoldi, L. Petrus, and V. Bilik, Coll. Czech. Chem. Comm., 1978, 43, 1476. [Pg.187]

The unsaturated phosphonates typified in (2) do not conform with Hudson s isorotation rule the conformational free energy for the dimethylphosphono group was found to be 8.34 kJ mol and its anomeric effect was calculated to be 2,33 kJ mol .  [Pg.188]


Carbohydrate Chemistry, Royal Society of Chemistry, vol. 31, 2000 R41 Anonymous (U.K.), NMR Spectroscopy and Conformational Features , p. 312... [Pg.4]

N.M.R. Spectroscopy and Conformational Features Theoretical and General Considerations Acyclic Systems Furanose Systems Pyranose Systems Oligosaccharides Nucleosides Other Molecules... [Pg.297]


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Conformation spectroscopy

NMR Spectroscopy and Conformational Features

Spectroscopy and Conformational Features of Carbohydrates

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