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Special Topic 6.14 Photochemical synthesis of large rings

Special Topic 6.14 Photochemical synthesis of large rings [Pg.320]

Facile synthesis of isooxyskytanthine (300), a monoterpene alkaloid, was performed by photoreductive intramolecular cyclization of the 5-oxocyclopentanecarboxamide [Pg.322]

Case Study 6.23 Organic synthesis - Diels-Alder trapping of photoenols [Pg.324]

The total synthesis of cytotoxic agents hamigerans was achieved via the photoenoliza-tion of substituted benzaldehydes and the subsequent Diels Alder (dark) reaction.983 Two species, E- and Z-isomers of 305, while being interconverted by E Z [Pg.324]

Case Study 6.24 Photoremovable protecting groups - 2,5-dimethyl-phenacyl chromophore [Pg.326]




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Large ring synthesis

Ring photochemical

Ring, large

Special topics

Synthesis special

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