Spatial Resolution Considerations

In an FT-IRI experiment, no physical apertures are used to limit the illumination area of the IR beam. Instead, an array of IR detector elements is used to collect the projected image of the unmasked IR beam on the sample. While FPA systems dramatically improve the rate at which IR images can be collected, the spatial resolution is poorer than that of a confocal FT-IRM microscope because an FT-IRI instrument cannot operate in a confocal arrangement. 

---

The CARS signal is generated within the common overlap-volume of the three incident beams. This boxcar technique increases the spatial resolution considerably, which may reach values below 1 mm. 

With the use of appropriate transmission optics, high focusing of the laser light is carried out and the extension of the optical probe is considerably reduced. Accordingly, laser-based techniques offer the possibility of measurements of high spatial resolution. 

All considerations for measurements of single spot Raman spectra also hold for mapping because the measuring technique is essentially identical. The spatial resolution in a map depends also on the distance between the single points and can be altered from map to map. By increasing the distance, the spatial resolution... 

Taking into account these considerations, improved spatial resolution (in contrast to conventional mapping techniques) may be obtained by three ways ... 

Interrogating the light from stars and the absorption features of atoms and molecules in-between requires some fairly complicated optics in the form of a telescope. However, the telescopes are not restricted to the parts of the electromagnetic spectrum that you can see but use radiation from microwaves to gamma rays to observe the Universe. There is too much to learn about the optics or even adaptive optics of telescopes to be discussed here but there are some properties of telescopes that we must know because they are important for the identification of atoms and molecules. We shall discuss three telescope considerations the atmosphere, the spatial resolution and the spectral resolution. 

Signal-to-noise considerations make most neutron-based explosive detection approaches very difficult to implement. The basis for combining multiple detection approaches (FNA, along with thermal gamma detection and neutron transmission spectroscopy) in a FNAP application that preserves the small volume advantage of a APSTNG remains to be established. There are distinct advantages associated with the API approach, but the concomitant reductions in available neutron flux, issues of tube lifetime, and the intrinsic poor spatial resolution must be taken into consideration for potential applications. 

In conventional gas electron diffraction experiments, an effusive beam is used in which vibrational levels of molecules are thermally populated and the width of a peak in a radial distribution curve is determined by thermally averaged mean amplitudes. When a molecular beam or a free jet is used, mean amplitudes could become small, since the contribution from the vibrationally excited levels is reduced significantly. As a consequence, sharper peaks are expected in the radial distribution curve, and the spatial resolution of the snapshot could be improved. However, it seems that the observed peaks in the radial distribution curve are considerably broad even though a molecular beam is used. There could be some reasons to have such broadened peaks in the radial distribution curve. 

Consideration of Surface Tool Concerns. Reasonably fast data acquisition, small probing beam size (allowing both faster sputter profiling and spatial resolution) and semiquantitative data analysis, give AES a primary role in each of these two experiments. 

Consideration of Surface Analysis Concerns. The researchers in this study used a wide range of surface and other tools, taking appropriate advantage of the strengths of the various methods. Previous work had shown that AES and XPS could be used to study chromate films without unreasonable problems and provided a basis for the current study. XPS was used to obtain specific chemical information while AES was used whenever spatial resolution and electron imaging were desired. RBS and electron microprobe work was used to analyze composition structures of thicker layers. 

As Brenguier (2003) noted, a contributing factor to the uncertainty is drizzle in clouds that form in the atmospheric boundary layer (ABL). In particular, this circumstance illustrates the importance of the adequate retrieval of cloud cover dynamics in the ABL. Another problem is connected with consideration (parameterization) of small-scale processes in the ABL and their non-linearity. For instance, aerosols acting as cloud concentration nuclei (CCN) can be determined from upward motions at the cloud bottom which should be reproduced at a spatial resolution (in the horizontal) of the order of 100 m. The present parameterization schemes still do not meet these requirements. 

---