Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Silicon-transition-metal complexes alkynes

Carbon-shielding tensors, alkene and alkyne transition metal complexes, 1, 472 Carbon—silicon bond formation... [Pg.76]

One of the first observed C/Cl exchanges on Si mediated by a transition metal complex was the stoichiometric cleavage of the alkyne-silicon bond shown in Eq. (44) (28). In the presence of ethanol, the Si—Cl bond is solvolyzed and an active Pt species is formed with the liberation of diethyl ketal. Under these conditions, the process is catalytic and Zeise s salt (K[(C2H, )RC13 ]) is also an effective catalyst precursor [Eq. (45)]. [Pg.223]

Although for the catalytic transformations of organosilicon compounds only hydrosilylation is well known as industrially important process, in the last 20 years other reactions of silicon compounds catalyzed by transition metal complexes have been discovered and developed. They include double (bis)silylation of alkenes and alkynes, silylative coupling of alkenes and alkynes with vinylsi-lanes, dehydrocoupling of hydrosilanes, silylformylation and silylcarbonylation of unsaturated compounds, and dehydrogenative silylation of alkenes and alkynes with hydrosilanes. Only the latter, as related to hydrosilylation (and very often its side reaction), has been discussed here (13). [Pg.1255]

The hydrosilylation of alkenes and alkynes catalyzed by transition metal complexes is often accompanied by side reactions such as isomerization, polymerization, and hydrogenation of unsaturated compounds and/or redistribution and dehydrogenation of silicon hydrides as well as reactions in which both substrates take part, such as dehydrogenative silylation (4,13). The latter reaction, which in certain conditions permits direct production of unsaturated silyl compound, has been a subject of intense study over the last two decades. [Pg.1259]

In an interesting contrast to the analogous silicon and germanium systems, catalytic addition of the unactivated hexamethyldistannane to unsaturated substrate readily occurs with the common palladium catalysts Pd(PPh3)4 or Pd(dba)2. In fact, prior to 1991 this was the only distannane investigated for addition reactions. The first example of transition metal-catalyzed double stannylation of unsaturated molecules, palladium-catalyzed cis addition of hexamethyldistannane to 1-alkynes, was reported in 1983 by Mitchell and co-workers.66 More recently, the system has been extended to include other substrates and both the hexaethyl- and the hexabutyldistannanes. All examples reported involve the use of a Pd(0) complex as the catalytic species. [Pg.220]


See other pages where Silicon-transition-metal complexes alkynes is mentioned: [Pg.726]    [Pg.345]    [Pg.209]    [Pg.113]    [Pg.198]    [Pg.70]    [Pg.198]   
See also in sourсe #XX -- [ Pg.44 , Pg.45 , Pg.46 , Pg.54 ]

See also in sourсe #XX -- [ Pg.44 , Pg.45 , Pg.46 , Pg.54 , Pg.55 ]




SEARCH



Alkyne complexe

Alkyne complexes

Alkynes metalated

Alkynes metallation

Alkynes transition metals

Complexes, alkyne-metal

Metal alkynes

Metalation alkynes

Metallic silicon

Silicon alkynes

Silicon complexes

Silicon transition metals

Silicon-metal complexes

Silicon-transition-metal complexes

Siliconates complex

Transition metals alkyne complexes

© 2024 chempedia.info