Shore hardnesses

Mohs hardness values may vary Shore hardness number is derived from rebound height of standard steel ball when dropped on material from standard height. 

Plasticizer Efficiency. This is a measure of the concentration of plasticizer required to impart a specified softness to PVC. Such a softness of material may be measured as a British Standard Softness (BSS) or a Shore hardness (Pig. 1). Por a given acid constituent of plasticizer ester, ie, phthalate, adipate, etc, plasticizer efficiency decreases as the carbon number of the alcohol chain increases, eg, for phthalate esters efficiency decreases in the order DBP > DIHP > DOP > DINP > DIDP > DTDP. An additional six parts per hundred in PVC of DIDP rather than DOP is required to give a hardness of Shore 80 when ah. other formulation ingredients remain constant. The consequence of this depends on the overall formulation and product costs. In addition to size of the carbon number of the alcohol chain, the amount of branching is also significant the more linear isomers are of greater efficiency. 

At strains over 300% the stress occurs mostiy in the amorphous regions up to the point where the sample breaks. AH of the grades exhibit permanent set, and the curves of grades with a Shore Hardness of 55 and higher exhibit a yield point. This means that parts have to be designed for low strains to stay within the area of elastic recovery. Special grades of elastomer are available to provide hydrolysis resistance (194), improved heat aging (195), and improved uv-stabihty (196). 

The crystallization kinetics defines the open time of the bond. For automated industrial processes, a fast crystallizing backbone, such as hexamethylene adipate, is often highly desirable. Once the bond line cools, crystallization can occur in less than 2 min. Thus, minimal time is needed to hold or clamp the substrates until fixturing strength is achieved. For specialty or non-automated processes, the PUD backbone might be based on a polyester polyol with slow crystallization kinetics. This gives the adhesive end user additional open time, after the adhesive has been activated, in which to make the bond. The crystallization kinetics for various waterborne dispersions were determined by Dormish and Witowski by following the Shore hardness. Open times of up to 40 min were measured [60]. 

Shoreharte, /. Shore hardness, slameslsch, a. Siamese, Siam, slbirisch, a. Siberian. 

Shore hardness It is the indentation hardness of a material as determined by the depth of an indentation made with an indenter of the Shore type durometer. The scale reading on this durometer is from zero (corresponding to 0.100 in. depth) to 100 for zero depth. The Shore A indenter has a sharp point, is spring-loaded, and is used for the softer plastics. The Shore B indenter has a blunt point, is spring-loaded at a higher value, and is used for harder plastics. 

Figure 7-10 shows durometer scale relationships and hardness ranges. The letter designations refer to the Shore hardness test (Chapter 5, MECHANICAL PROPERTY, Hardness). 

Shear modulus, polyamide, 138 Sheet molding compounds (SMCs), 30 Shoe sole products, 205 Shore hardness gauge, 243 Side-chain liquid crystalline polymers, 49 Side reactions, in transition metal coupling, 477... 

ISO 868, Plastics and ebonite - Determination of indentation hardness by means of a durometer (Shore hardness), 1985. 

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