Ship-in-bottle synthesis

Fig. 7 Methods for ship-in-bottle synthesis of (salen)Mn complexes inside the pores of zeolites...

Circulation flow system, measurement of reaction rate, 28 175-178 Clausius-Clapeyron equation, 38 171 Clay see also specific types color tests, 27 101 compensation behavior, 26 304-307 minerals, ship-in-bottle synthesis, metal clusters, 38 368-379 organic syntheses on, 38 264-279 active sites on montmorillonite for aldol reaction, 38 268-269 aldol condensation of enolsilanes with aldehydes and acetals, 38 265-273 Al-Mont acid strength, 38 270-271, 273 comparison of catalysis between Al-Mont and trifluorometfaanesulfonic acid, 38 269-270... 

Fischer-Tropsch catalysis, 38 332 hydroformylation activity, 38 329-330 in NaY supercages, reversible formation and isomer transformation, 38 374 phosphino polystyrene support, 38 39 reactivity, 38 317-319, 323 ship-in-bottle synthesis in NaY zeolite supercages, 38 368-370... 

Ship-in-Bottle Synthesis of Sterically Crowded Fe-Phthalocyanines in NaY Zeolite Hosts and Their Catalytic Behavior in Regioselective Oxidation of Alkanes... 

Ship-in-Bottle Synthesis of Fe-Phthalocyanines in NaY and Their Catalytie Behavior 34]... 

Fukuoka, A., Higashimoto, N., Sakamoto, Y., Sasaki, M., Sugimoto, N., Inagaki, S., Fukushima, Y. and Ichikawa, M. Ship-in-bottle synthesis and catalytic performances of platinum carbonyl clusters, nanowires, and nanoparticles in microporous and mesoporous materials, Catal. Today, 2001, 66, 23-31. 

Drozdova, L., Novakova J, Schulz-Ekloff G, Jaeger N. I. Ship-in-bottle synthesis of palladium carbonyl complexes in NaY and NaX zeolites via the... 

A. Ship-in-Bottle Synthesis of Metal Clusters in Zeolites and Clay Minerals Structures and Reactivity of Metal Clusters in Zeolites... 

Fig. 27. Pictorial representation of ship-in-bottle synthesis of RhelCO), in NaY supercages via reductive carbonylation of Rh -NaY.

An alternative to framework ion manipulation is the occlusion of catalytic molecules onto zeolite crystals using ship-in-bottle synthesis. The choice between these two methods may be best guided by the need for chemical and thermal stability in the catalytic reactions studied. 

Brabec, L. and Novakova, J. (2001) Ship-in-bottle synthesis of anionic Rh carbonyls in faujasites. J. Mol. Catal. A, 166, 283—292. Gurin, V.S., Petranovskii, N.P. and Bogdanchikova, N.E. (2002) Metal clusters and nanoparticles assembled in zeolites an example of stable materials with controllable particle size. Mater. Sci. Eng. C, C19, 327-331. 

The first inverse of the ship-in-bottle synthesis, in which the zeolite cage is constructed around a porphyrin template, was reported by Li and Zhan. " The Fe(II) and Mn(II) derivatives of tetra(Af,A, Af-trimethylanilinium)porphyrin and H2(TMPyP) were used as cationic templates in zeolite hydrothermal synthesis. Attempts to incorporate an anionic porphyrin species, metallo-tetra(4-sulfunatophenyl)por-phyrin, were unsuccessful and trials with neutral TPP species resulted in trace encapsulation. High activity for the catalytic oxidation of cyclohexene by terf-butyl hydroperoxide was reported. 

Pan L, Liu H, Lei X, Huang X, Olson DH, Turro NJ, et al. RPM-1 a recyclable nanoporous material suitable for ship-in-bottle synthesis and large hydrocarbon sorption. Angew Chem Int Ed 2003 42 542-6. 

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