Magnetization, saturation

Saturated absorption Saturated brine Saturation Saturation bonding Saturation magnetization Sauerkraut Sauflon Sauflon PW S. aureus... 

The saturation magnetization, J), is the (maximum) magnetic moment per unit of volume. It is easily derived from the spia configuration of the sublattices eight ionic moments and, hence, 40 ]1 per unit cell, which corresponds to = 668 mT at 0 K. This was the first experimental evidence for the Gorter model (66). The temperature dependence of J) (Fig. 7) is remarkable the — T curve is much less rounded than the usual BdUouia function (4). This results ia a relatively low J) value at RT (Table 2) and a relatively high (—0.2%/° C) temperature coefficient of J). By means of Mitssbauer spectroscopy, the temperature dependence of the separate sublattice contributions has been determined (68). It appears that the 12k sublattice is responsible for the unusual temperature dependence of the overall J). 

Fig. 9. Temperature dependences of the saturation magnetization AF, the coercivity FF and the Kerr rotation 9j for a 50-nm GdQ 24 0 oi o 75...

Iron—Aluminum and Iron—Aluminum—Silicon Alloys. The influence of aluminum on the physical and magnetic properties of iron is similar to that of silicon, ie, stabilization of the bcc phase, increased resistivity, decreased ductility, and decreased saturation magnetization, magnetocrystalline anisotropy, and magnetostriction. Whereas Si—Ee alloys are well estabHshed for electrical appHcations, the aluminum—iron alloys have not been studied commercially. However, small (up to ca 0.3%) amounts of A1 have been added to the nonoriented grades of siHcon steel, because the decrease in ductiHty is less with A1 than with Si. 

The mechanism for coercivity in the Cr—Co—Fe alloys appears to be pinning of domain walls. The magnetic domains extend through particles of both phases. The evidence from transmission electron microscopy studies and measurement of JT, and anisotropy vs T is that the walls are trapped locally by fluctuations in saturation magnetization. 

Fig. 6. Changes in ( coercive force, (----) saturation magnetization Af, and (— —) coercive squareness ratio, A, of Co—Cr—Ta/Cr films...

These are meant to be used with a capacitor to tune a filter circuit, with resonances in the audio frequency range for reducing and filtering the harmonics or communication frequencies. They provide a near short-circuit for the required harmonics to filter them out of circuit. They may be single-phase or three-phase and connected in series or parallel of the capacitor circuit and may have a fixed or variable reactance, rated continuously with saturated magnetic characteristics. They may incur heavy losses. 

The pressure sensitivity of the magnetic properties of the Invar alloys is indicated by extensive measurements of the coefficient of saturation magnetization change with pressure M dMJdP for various compositions as shown in Fig. 5.10. The exceedingly large values in the 30%-40% Ni range are evident and much in excess of the values for iron and nickel. The 30-wt% Ni composition in the fee phase is the most sensitive to pressure, whereas this... 

Fig. 5.10. The pressure dependence of saturation magnetization for iron-nickel alloys shows a strong pressure dependence in the neighborhood of the Invar alloys (28.5 to 40-at. % nickel in the fee phase). The shock data shown are in excellent agreement with the static high pressure data (after Wayne [69W01]).

The values for the atomic saturation magnetization at the absolute zero, ferromagnetic metals iron, cobalt, and nickel are 2.22, 1.71, and 0.61 Bohr magnetons per atom, respectively.9 These numbers are the average numbers of unpaired electron spins in the metals (the approximation of the g factor to 2 found in gyromagnetic experiments shows that the orbital moment is nearly completely quenched, as in complex ions containing the transition elements). 

Fig. 2. Predicted dependence of atomic saturation magnetic moment a a as f unction of number of atomic d electrons.

For alloys of iron, cobalt, nickel, and copper the calculated values of saturation magnetic moments agree closely with the observed values in particular, the maximum value of about 2.48 magnetons at electron number about 26.3 is reproduced by the theory. There is, however, only rough agreement between the observed and calculated values of the Curie temperature. 

An obvious refinement of the simple theory for cobalt and nickel and their alloys can be made which leads to a significant increase in the calculated value of the Curie temperature. The foregoing calculation for nickel, for example, is based upon the assumption that the uncoupled valence electrons spend equal amounts of time on the nickel atoms with / = 1 and the nickel atoms with J = 0. However, the stabilizing interaction of the spins of the valence electrons and the parallel atomic moments would cause an increase in the wave function for the valence electrons in the neighborhood of the atoms with / = 1 and the parallel orientation. This effect also produces a change in the shape of the curve of saturation magnetization as a function of temperature. The details of this refined theory will be published later. 

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